Towards a sustainable electrochemical activation for recycling CO2: synthesis of bis-O-alkylcarbamates from aliphatic and benzyl diamines

文献情報

出版日 2017-08-29

DOI 10.1039/C7RE00101K

インパクトファクター 4.239

著者

Gianpiero Forte, Isabella Chiarotto, Frank Richter, Vinh Trieu, Marta Feroci

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要旨

Carboxylation of aliphatic and benzyl diamines with electrochemically activated CO2 led to the synthesis of bis-O-alkyl carbamates in high yields. Reaction conditions, including the geometry of the electrochemical cell, were discussed and optimized. This resulted in a significant reduction of unwanted material associated with the reaction, overcoming the economic and environmental restrictions to its application on large scale.

掲載誌

Reaction Chemistry & Engineering

CiteScore: 0

自己引用率: 8.8%

年間論文数: 284

Reaction Chemistry & Engineering is an interdisciplinary journal reporting cutting-edge research focused on enhancing the understanding and efficiency of reactions. Reaction engineering leverages the interface where fundamental molecular chemistry meets chemical engineering and technology. Challenges in chemistry can be overcome by the application of new technologies, while engineers may find improved solutions for process development from the latest developments in reaction chemistry. Reaction Chemistry & Engineering is a unique forum for researchers whose interests span the broad areas of chemical engineering and chemical sciences to come together in solving problems of importance to wider society. All papers should be written to be approachable by readers across the engineering and chemical sciences. Papers that consider multiple scales, from the laboratory up to and including plant scale, are particularly encouraged.

Towards a sustainable electrochemical activation for recycling CO2: synthesis of bis-O-alkylcarbamates from aliphatic and benzyl diamines

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Reaction Chemistry & Engineering

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