Probing the first steps of photoinduced free radical polymerization at water–oil interfaces

文献情報

出版日 2017-10-31

DOI 10.1039/C7PY01414G

インパクトファクター 5.582

著者

Denisa Darvasiová, Zuzana Barberiková, Anna Eibel, Max Schmallegger, Georg Gescheidt, Michal Zalibera, Dmytro Neshchadin

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要旨

Phosphanoyl radicals, produced by α-photocleavage of exclusively octane-soluble acylphosphane oxides, rapidly react with both water- and octane-soluble monomers in water-in-octane microemulsions. The presented mechanistic insights open the possibility for the tailored construction of photo-generated copolymers comprising polar and non-polar blocks at the same time.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

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Probing the first steps of photoinduced free radical polymerization at water–oil interfaces

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