Origin of nanostructural inhomogeneity in polymer-network gels

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出版日 2017-07-14

DOI 10.1039/C7PY01035D

インパクトファクター 5.582

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要旨

Polymer-network gels often display nano- to microstructural spatial inhomogeneity of their polymer-segmental and crosslinking densities, especially if they are formed by uncontrolled free-radical crosslinking copolymerization of mono- and multifunctional monomers and crosslinkers. This structural complexity markedly affects their optical clarity, mechanical strength, and permeability, which is of central relevance for their performance in everyday-life and high-tech products. This review summarizes and inter-relates a rich amount of existing studies on the origin of this inhomogeneity. It arcs from early fundamental work in the 1990s, development and assessment of highly ideal and super tough model-network gels in the 2000s, up to more recent work on hierarchically structured gels.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

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Origin of nanostructural inhomogeneity in polymer-network gels

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