Fe-Porphyrin functionalized microporous organic nanotube networks and their application for the catalytic olefination of aldehydes and carbene insertion into N–H bonds

文献情報

出版日 2017-05-31

DOI 10.1039/C7PY00530J

インパクトファクター 5.582

著者

Minghong Zhou, Hui Zhang, Linfeng Xiong, Zidong He, Tianqi Wang, Yang Xu, Kun Huang

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要旨

Novel meso-tetraphenylporphyrin iron(III) chloride (Fe(TPP)Cl) functionalized microporous organic nanotube networks (Fe(TPP)Cl-MONNs) were successfully synthesized by an in situ hyper-crosslinking reaction between core–shell bottlebrush copolymers and Fe(TPP)Cl. The obtained Fe(TPP)Cl-MONN catalyst possesses a hierarchical porous structure, large surface area and good stability, which exhibits high catalytic activity and excellent reusability in the olefination of aldehydes and carbene insertion into N–H bonds with ethyl diazoacetate.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

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Fe-Porphyrin functionalized microporous organic nanotube networks and their application for the catalytic olefination of aldehydes and carbene insertion into N–H bonds

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