A Brønsted acid-promoted asymmetric intramolecular allylic amination of alcohols

文献情報

出版日 2017-12-07

DOI 10.1039/C7OB02599H

インパクトファクター 3.876

著者

Jianqiao Zhou, Hexin Xie

原文を見る

要旨

Reported herein is a chiral Brønsted acid-catalyzed asymmetric intramolecular allylic amination reaction, allowing facile access to a range of biologically interesting chiral 2-substituted hydroquinolines in up to 90% yield and with up to 93% ee. Furthermore, a significant effect of an N-protecting group was observed in this asymmetric process.

掲載誌

Organic & Biomolecular Chemistry

CiteScore: 3.4

自己引用率: 10.3%

年間論文数: 1041

Organic & Biomolecular Chemistry (OBC) publishes original and high impact research and reviews in organic chemistry. We welcome research that shows new or significantly improved protocols or methodologies in total synthesis, synthetic methodology or physical and theoretical organic chemistry as well as research that shows a significant advance in the organic chemistry or molecular design aspects of chemical biology, catalysis, supramolecular and macromolecular chemistry, theoretical chemistry, mechanism-oriented physical organic chemistry, medicinal chemistry or natural products. Articles published in the journal should report new work which makes a highly-significant impact in the field. Routine and incremental work is generally not suitable for publication in the journal. More details about key areas of our scope are below. In all cases authors should include in their article clear rationale for why their research has been carried out.

A Brønsted acid-promoted asymmetric intramolecular allylic amination of alcohols

文献情報

おすすめジャーナル

関連文献

Mode specific photodissociation of CS2+via the A2Πu state: a time-sliced velocity map imaging study

Intermediates and kinetics for phenolgasification in supercritical water

Steering the enzymatic activity of proteins by ionic liquids. A case study of the enzyme kinetics of yeast alcohol dehydrogenase

Optically probing nanoemulsion compositions

Hydrogen bonding of water in 3-methylpyridine studied by O 1s X-ray emission and absorption spectroscopy

Reorganization energy and pre-exponential factor from temperature-dependent experiments in electron transfer reactions. A typical example: the reduction of tert-nitrobutane

Polymer dynamics in responsive microgels: influence of cononsolvency and microgel architecture

The electric field as a novel switch for uptake/release of hydrogen for storage in nitrogen doped graphene

A quantitative study of the clustering of polycyclic aromatic hydrocarbons at high temperatures

Reversible formation of a PdCx phase in Pd nanoparticles upon CO and O2 exposure

こちらもおすすめ

カルボニル基が付いた5-氰基-1-{[(2-メチル-2-プロpanyl)オキシ]カーボンイル}1H-吲哚-2-イリド-2-ボリン酸はどのように保存すればよいですか？

tert-ブチル2-クロロメチルピリジン-3-基炭酸エステルの市場動向や研究トレンドはどうですか？

聚二季戊四醇六丙烯酸酯はどの業界で使用されていますか？

1-氯-5-硝基异喹啉の市場動向や研究トレンドはどうですか？

2-チロール-5-メチルスルフェニル-3-trifルオルメチルベンゼンはどのように合成されますか？

p-トールイルマグネシウムブロミドの物理化学的性質は何ですか？

1-(5-甲基-2-硫化素基)プロパン-1-酮の市場動向や研究トレンドはどうですか？

十一碳烯酰甘氨酸を取り扱う際の実験室安全事項は何ですか？

1H,1H-全氟-3,6-二氧杂葵-1-醇を取り扱う際の実験室安全事項は何ですか？

3-(4-(フルオロメチルオキシ)フェニル)-1,2,4-オキサジアゾール-5-カルボハイドライドは安全ですか？

掲載誌

Organic & Biomolecular Chemistry

おすすめ化合物

1-Bromo-4-tert-butyl-2-iodo-benzene

7-(Bromomethyl)-1-methyl-1H-indazole

[(2-chlorophenyl)methyl](ethyl)amine

2-(Bromomethyl)-4-methyl-1-nitrobenzene

N-[4-(Cyanoethynyl)phenyl]-16-oxo-4,7,10,13-tetraoxa-17-azahenicos-1-yn-21-amide

おすすめサプライヤー