Steering on-surface reactions with self-assembly strategy

文献情報

出版日 2017-11-13

DOI 10.1039/C7CP06177C

インパクトファクター 3.676

著者

Jingxin Dai, Kai Wu

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要旨

The control of assembly structures that subsequently help achieve viable functionalities has been one of the key motivations for the exploration of surface molecular assembly. In terms of its functionality and applicability, the assembly is explored as a strategy to steer on-surface reactions primarily by two methods: assembly-assisted and assembly-involved reactions. The functions of the self-assembly strategy are threefold: tweaking reaction selectivities, steering reaction pathways, and directing reaction sites. The governing principle herein is that the assembly strategy can apply a surface confinement effect that affects the energy barrier and pre-exponential factor of the Arrhenius equation for the dynamics of the target reaction. Development of such a strategy may reveal new routes to steer on-surface reactions and even single molecule properties in surface chemistry.

掲載誌

Physical Chemistry Chemical Physics

CiteScore: 5.5

自己引用率: 10.3%

年間論文数: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.