Spring-like motion caused large anisotropic thermal expansion in nonporous M(eim)2 (M = Zn, Cd)

文献情報

出版日 2017-07-11

DOI 10.1039/C7CP03937A

インパクトファクター 3.676

著者

Zhanning Liu, Chenxi Liu, Qiang Li, Jun Chen, Xianran Xing

原文を見る

要旨

Two nonporous coordination polymers were found to possess large anisotropic thermal expansion, which was derived from the flexible structures. A “spring-like” thermal motion was proposed to illustrate the mechanism. Compound Cd(eim)2 (eim = 2-ethylimidazole) possesses large linear and reversible thermal expansion properties and the emission intensity shows a linear decrease with temperature, making it a candidate for thermo-responsive materials.

掲載誌

Physical Chemistry Chemical Physics

CiteScore: 5.5

自己引用率: 10.3%

年間論文数: 3036

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