From oxidative degradation to direct oxidation: size regimes in the consecutive reaction of cationic tantalum clusters with dioxygen
文献情報
J. F. Eckhard, D. Neuwirth, M. Tschurl, U. Heiz
Cationic tantalum clusters (Ta9–12+) are reacted with molecular oxygen under multi-collision conditions in the gas phase in order to analyze the reaction kinetics. Clusters in this transitional size regime demonstrate reaction pathways associated with smaller clusters that mainly degrade upon oxidation (loss of a TaO unit) and those of larger clusters that are oxidized in absence of fragmentation. This behavior is exemplified by Ta9+, which generates Ta9O14+ and Ta4O11+, and the underlying, intricate reaction network is subsequently investigated. Ultimately, rate constants, reaction pathways and final products of cluster sizes up to n = 40 are compared to reveal the size-dependent oxidation behavior.
関連文献
Miniaturized biological and electrochemical fuel cells: challenges and applications
Jie Yang, Sasan Ghobadian, Payton J. Goodrich, Reza Montazami, Nastaran Hashemi
DOI: 10.1039/C3CP50804H
Towards systematically improvable models for actinides in condensed phase: the electronic spectrum of uranyl in Cs2UO2Cl4 as a test case
André Severo Pereira Gomes, Christoph R. Jacob, Florent Réal, Lucas Visscher, Valérie Vallet
DOI: 10.1039/C3CP52090K
Mg composition dependent band offsets of Zn1−xMgxO/ZnO heterojunctions
H. H. Zhang, X. H. Pan, B. Lu, J. Y. Huang, P. Ding, W. Chen, H. P. He, J. G. Lu, S. S. Chen, Z. Z. Ye
DOI: 10.1039/C3CP51156A
Starburst triarylamine based dyes bearing a 3,4-ethylenedioxythiophene linker for efficient dye-sensitized solar cells
Li-Lin Tan, Hong-Yan Chen, Li-Feng Hao, Yong Shen, Li-Min Xiao, Jun-Min Liu, Dai-Bin Kuang, Cheng-Yong Su
DOI: 10.1039/C3CP51633D
Enantiotopic discrimination and director organization in the twist-bend nematic phase
Cristina Greco, Geoffrey R. Luckhurst, Alberta Ferrarini
DOI: 10.1039/C3CP52222A
Interaction of electrolyte molecules with carbon materials of well-defined porosity: characterization by solid-state NMR spectroscopy
Lars Borchardt, Martin Oschatz, Silvia Paasch, Stefan Kaskel, Eike Brunner
DOI: 10.1039/C3CP52283K
Evidence of confinement of the π plasmon in periodically rippled graphene on Ru(0001)
Antonio Politano, Davide Campi
DOI: 10.1039/C3CP51954F
Compact large area and high-quality Au film with a hierarchical structure and its application in SERS
Youyi Xia, Tenjiao Li, Jun Chen
DOI: 10.1039/C3CP51080H
Effect of the state of distribution of supported Pt nanoparticles on effective Pt utilization in polymer electrolyte fuel cells
Makoto Uchida, Young-Chul Park, Katsuyoshi Kakinuma, Hiroshi Yano, Donald A. Tryk, Takeo Kamino, Hiroyuki Uchida, Masahiro Watanabe
DOI: 10.1039/C3CP51801A
こちらもおすすめ
2-メトキシ-4-(メチルスルフィニル)アミンの主な用途は何ですか?
2-メトキシ-4-(メチルスルフィニル)アミンは、主に医薬品および農薬の製造に使用されます。また、合成化学の一部として研究用材料としても利用されます。
4,6-二氯-N-甲基ピラミジンアミンの代替品はありますか?
代替品としては、4,6-二クロロピラミジンアミンや他のピラミジン系化合物が考えられます。ただし、目的と用途によって最適な代替品は異なります。
6-氯-4-甲基-1H-吲哚を含む廃棄物はどのように処理すべきですか?
6-氯-4-甲基-1H-吲哚の廃棄物は、適切な容器に収集し、密閉して保管します。温度は常温、湿度は低く、直射日光を避けて保管することを推奨します。廃棄処理は専門...
2-フローユロ-4-(トリフルオロメチル)ベンゾイドについて「に適用される法規ガイドラインは何ですか」
2-フローユロ-4-(トリフルオロメチル)ベンゾイドのCAS番号は207974-08-1です。この化合物はGHS分類で毒性物質と有害な反応物質として分類されます...
4-ニトロフェニルN-[(ベンゼルオキシルカーボンイル]グリシングリシングリシン酸はどのように保存すればよいですか?
4-ニトロフェニルN-[(ベンゼルオキシルカーボンイル]グリシングリシングリシン酸は、室温で暗所に保管し、乾燥した環境で保存することを推奨します。容器は密閉性の...
イソデスロラタドリンの代替品はありますか?
イソデスロラタドリンの代替品としては、デスロラタドリンや他の抗ヒスタミン薬が挙げられます。具体的には、デスロラタドリン、ラセカミド、フェルタドリンなどが、症状や...
5-甲氧基-1,2,3,4-四氢异喹啉盐酸盐はどのように合成されますか?
5-甲氧基-1,2,3,4-四氢异喹啉盐酸盐の一般的な合成方法は、メタノール中で5-メトキシ-1,2,3,4-四ヒュドロイソキシンを塩酸で塩化します。この反応で...
4-アミノ-5-メトキシ-2-トルエンサルホニック酸についての法規ガイドラインは何ですか?
CAS番号6471-78-9の4-アミノ-5-メトキシ-2-トルエンサルホニック酸は、GHS分類では corrosive(腐食性)と識別されます。EUのREAC...
甲基孕酮を取り扱う際の実験室安全事項は何ですか?
甲基孕酮の取り扱いは、PPE(個人保護具)の使用が必要な重要な安全事項を伴います。防塵マスク、ゴーグル、手袋を着用することが推奨されます。ドラフトチャンバーを使...
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.














