One-pot synthesis of fluorescent 2,4-dialkenylindoles by rhodium-catalyzed dual C–H functionalization

文献情報

出版日 2016-12-20

DOI 10.1039/C6QO00755D

インパクトファクター 5.281

著者

Hui Chen, Cong Lin, Chunhua Xiong, Zhanxiang Liu, Yuhong Zhang

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要旨

Herein, a one-pot approach to the synthesis of 2,4-dialkenylindoles by rhodium-catalyzed dual C–H alkenylation and decarboxylation of indole-3-carboxylic acids with alkenes is described. This protocol provided facile access to diverse 2,4-dialkenylindoles, which were found to exhibit intense fluorescence in the range of 472–530 nm with a quantum yield of up to 0.57 in CH2Cl2.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

One-pot synthesis of fluorescent 2,4-dialkenylindoles by rhodium-catalyzed dual C–H functionalization

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