Pd(ii)-Catalyzed oxidative dearomatization of indoles: substrate-controlled synthesis of indolines and indolones

文献情報

出版日 2016-12-01

DOI 10.1039/C6QO00698A

インパクトファクター 5.281

著者

Xinxin Fang, Shang Gao, Zijun Wu, Hequan Yao, Aijun Lin

原文を見る

要旨

A Pd(II)-catalyzed oxidative Wacker-type cyclization/dearomatization of 2,3-disubstituted indoles with molecular oxygen as the oxidant has been developed. This strategy provides straightforward access to diverse fused indolines bearing C2-oxygenated quaternary stereocenters with good functional group tolerance and high atom economy. Meanwhile, a Pd(II)-catalyzed oxidation/dearomatization of 2-substituted indoles is also presented, which enables the facile synthesis of indolones.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Pd(ii)-Catalyzed oxidative dearomatization of indoles: substrate-controlled synthesis of indolines and indolones

文献情報

おすすめジャーナル

関連文献

Micromechanical measurements of the effect of surfactants on cyclopentane hydrate shell properties

Contents list

Real-space numerical grid methods in quantum chemistry

Front cover

Enhanced stability of Zn2SnO4 with N719, N3 and eosin Y dye molecules for DSSC application

Ullmann coupling mediated assembly of an electrically driven altitudinal molecular rotor

Effect of strong phonon–phonon coupling on the temperature dependent structural stability and frequency shift of 2D hexagonal boron nitride

Orbital free DFT versus single density equation: a perspective through quantum domain behavior of a classically chaotic system

Molecular design of electron transport with orbital rule: toward conductance-decay free molecular junctions

High order forces and nonlocal operators in a Kohn–Sham Hamiltonian

こちらもおすすめ

H-Leu-Ser-Lys-Leu-OH trifluoroacetate saltに適用される法規ガイドラインは何ですか？

Trimethyltin Chlorideの物理化学的性質は何ですか？

ニコール酸化物水和物の主な用途は何ですか？

(2,3-二甲基-2H-吲唑-6-基)boronic acidを取り扱う際の実験室安全事項は何ですか？

4-ブロモ-1-メトキシ-2-(2-メトキシエトオキシ)ベンゼンは安全ですか？

4,4-双(5-甲基-2-苯并噁唑基)二苯乙烯はどの業界で使用されていますか？

2,3,5,6-四氯-4-ピリジンスチオールを取り扱う際の実験室安全事項は何ですか？

替米沙坦ナトリウムとは何ですか？

TG 4-155はどのように合成されますか？

エチルヒドロキシキニリン-6-カルボキシ酸は適用される法規ガイドラインは何ですか？

掲載誌

Organic Chemistry Frontiers

おすすめ化合物

2-Oxo-1,2,3,4-tetrahydro-3-quinolinecarboxylic acid

L-Lysine,N6-[2-[[(1,1-dimethylethoxy)carbonyl]amino]benzoyl]-N2-[(9H-fluoren-9-ylmethoxy)carbonyl]-

4-Chloro-N-{[4-(dimethylamino)phenyl]carbamoyl}benzenesulfonamide

4-Cyanophenyl trifluoromethanesulfonate

Methyl hydroxy(2-thienyl)3-thienylacetate

おすすめサプライヤー