Efficient synthesis of (S,R)-Bn-Yanphos and Rh/(S,R)-Bn-Yanphos catalyzed asymmetric hydroformylation of vinyl heteroarenes

文献情報

出版日 2016-12-06

DOI 10.1039/C6QO00641H

インパクトファクター 5.281

著者

Biao Wei, Caiyou Chen, Cai You, Hui Lv

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要旨

A concise and efficient synthesis of (S,R)-Bn-Yanphos on a gram scale has been developed. When (S,R)-Bn-Yanphos was employed in Rh-catalyzed asymmetric hydroformylation of vinyl heteroarenes and allyl-1H-indole, it exhibited excellent catalytic activity, affording chiral heteroaryl aldehydes in good yields with high regio- and enantioselectivities (up to 96% ee).

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Efficient synthesis of (S,R)-Bn-Yanphos and Rh/(S,R)-Bn-Yanphos catalyzed asymmetric hydroformylation of vinyl heteroarenes

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