Calcium mediated C–F bond substitution in fluoroarenes towards C–chalcogen bond formation

文献情報

出版日 2016-10-20

DOI 10.1039/C6QO00515B

インパクトファクター 5.281

著者

Pintu Maity, Sabir Ahammed, Rabindra Nath Manna, Brindaban C. Ranu

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要旨

A new calcium chloride mediated C–F bond cleavage in electron deficient fluoroarenes followed by functionalisation via C–Se/Te bond formation has been achieved in the absence of any additive/ligand/organometallic reagent. A series of functionalised organo-selenides and -tellurides were obtained in high yields by this procedure. The precise role of calcium and the possible mechanism have been proposed based on DFT analysis.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Calcium mediated C–F bond substitution in fluoroarenes towards C–chalcogen bond formation

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