Cu-catalyzed one-pot synthesis of fused oxazepinone derivatives via sp2 C–H and O–H cross-dehydrogenative coupling

文献情報

出版日 2016-04-19

DOI 10.1039/C6QO00040A

インパクトファクター 5.281

著者

Zeyuan Zhang, Zhen Dai, Xinkun Ma, Yihan Liu, Xiaojun Ma, Wanli Li

原文を見る

要旨

An efficient Cu-catalyzed cascade reaction protocol was developed for the synthesis of fused oxazepinone derivatives via sp2 C–H and O–H cross-dehydrogenative coupling. A readily available catalyst, Cu2O, was used in this modular and convergent approach. An unusual Smiles rearrangement reaction was involved in this synthesis. Various reaction parameters were evaluated and optimized, and the target compounds were obtained in good-to-excellent yields.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Cu-catalyzed one-pot synthesis of fused oxazepinone derivatives via sp2 C–H and O–H cross-dehydrogenative coupling

文献情報

おすすめジャーナル

関連文献

Self-assembly of a hydrogen bonded framework from a gold phosphine complex with a pendant uracil group

Recent advancements and challenges of palladiumII-catalyzed oxidation reactions with molecular oxygen as the sole oxidant

Cu(ii)-mediated oxidative intermolecular ortho C–H functionalisation using tetrahydropyrimidine as the directing group

Membrane blotting for rapid detection of mercury(ii) in water

An efficient carbon precursor for gas phase growth of SWCNTs

Formation of polymer vesicles by simultaneous chain growth and self-assembly of amphiphilic block copolymers

Pair distribution function analysis of pressure treated zeolite Na-A

Zintl phase as dopant source in the flux synthesis of Ba1−xKxFe2As2 type superconductors

Polyfluorene with p-carborane in the backbone

Ag(i)-mediated formation of pyrophosphonate coupled with C–C bond cleavage of acetonitrile

こちらもおすすめ

3-(5-フェニル-2-ファイル)-プロパン酸の市場動向や研究トレンドはどうですか？

3- Chloro-1H-indazol-5-olはどのように保存すればよいですか？

二茂鐵是安全的吗？

L-(1-~13~C)メチオニンの市場動向や研究トレンドはどうですか？

1,3-フェニレンビスメチレンビスアクリレートは安全ですか？

丹参醇Aはどのように保存すればよいですか？

4-メチル-2-(1,1,1-三フロロ-2-メチルプロパニル)ピリドインとは何ですか？

N-フェニルベンジル-2-クロロ酢氨を取り扱う際の実験室安全事項は何ですか？

UCN-02を取り扱う際の実験室安全事項は何ですか？

N-[3-[2-(二甲基氨基)乙氧基]-4-甲氧基苯基]-2'-甲基-4'-(5-甲基-1,2,4-恶二唑-3-基)-[1,1'-联苯]-4-甲酰胺を取り扱う際の実験室安全事項は何ですか？

掲載誌

Organic Chemistry Frontiers

おすすめ化合物

Diethyl 1,1-cyclopropanedicarboxylate

N-[(9H-Fluoren-9-ylmethoxy)carbonyl]serine

Ethyl 6-Bromohexanoate

3-Bromo-9H-carbazole

Ammonium (Z)-2-(furan-2-yl)-2-(methoxyimino)acetate

おすすめサプライヤー