Controlled TfOH- or AuCl-catalyzed cycloisomerization and tandem hydrolytic defluorination of 1,2-allenyl perfluoroalkyl ketones

文献情報

出版日 2016-03-30

DOI 10.1039/C6QO00001K

インパクトファクター 5.281

著者

Can Xue, Xin Huang, Shangze Wu, Chunling Fu, Shengming Ma

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要旨

An efficient TfOH- or AuCl-catalyzed cycloisomerization reaction of easily available n-perfluoroalkyl 1,2-allenyl ketones occurring smoothly to form 2-perfluoroalkyl furans has been reported. In the presence of TfOH and H2O, a corresponding tandem hydrolytic defluorination afforded multi-substituted furan-2-yl n-perfluoroalkyl ketones.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Controlled TfOH- or AuCl-catalyzed cycloisomerization and tandem hydrolytic defluorination of 1,2-allenyl perfluoroalkyl ketones

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