Novel alkoxyamines for the successful controlled polymerization of styrene and methacrylates

文献情報

出版日 2017-02-10

DOI 10.1039/C6PY02190E

インパクトファクター 5.582

著者

Alexandre Simula, Miren Aguirre, Nicholas Ballard, Antonio Veloso, José R. Leiza, José M. Asua

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要旨

The design of alkoxyamine/nitroxide species capable of mediating the polymerization of both styrene and methacrylic monomers has been notoriously difficult. Herein, the nitroxide-mediated polymerization of styrene using a series of readily obtained alkoxyamines that were recently shown to control the polymerization of methyl methacrylate is presented. The robustness of the system is tested towards different temperatures and molecular weights. The influence of the substitution pattern in the nitroxide adducts on the polymerization of styrene is monitored through kinetic analyses. An alkoxyamine that can successfully mediate the homopolymerization of styrene and methyl methacrylate is presented. This alkoxyamine is subsequently utilized for the synthesis of PMMA-b-PS and PS-b-PBMA copolymers.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Novel alkoxyamines for the successful controlled polymerization of styrene and methacrylates

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