(−)-Riboflavin (vitamin B2) and flavin mononucleotide as visible light photo initiators in the thiol–ene polymerisation of PEG-based hydrogels

文献情報

出版日 2016-12-20

DOI 10.1039/C6PY02034H

インパクトファクター 5.582

著者

G. Kwandou, P. T. Spicer

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要旨

The photoinitiators used in light mediated hydrogelation have been limited due to cytotoxicity and solubility issues. Here we report the use of riboflavin and flavin mononucleotide as nontoxic, naturally occurring photoinitiators for the thiol–ene hydrogelation of functionalised poly(ethylene glycol). High Resolution Magic Angle Spinning (HRMAS) NMR spectroscopy and oscillatory rheometry were used to probe the efficiency of these initiators for this hydrogel system. The gelation and reaction progression could easily be manipulated using different initiator concentrations and light intensities.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

(−)-Riboflavin (vitamin B2) and flavin mononucleotide as visible light photo initiators in the thiol–ene polymerisation of PEG-based hydrogels

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