Blocked isocyanates: from analytical and experimental considerations to non-polyurethane applications

文献情報

出版日 2016-11-08

DOI 10.1039/C6PY01776B

インパクトファクター 5.582

著者

Marianne S. Rolph, Anna L. J. Markowska, Colin N. Warriner, Rachel K. O'Reilly

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要旨

In this review we aim to provide an introductory guide to blocked isocyanates, through discussion on different examples of blocking groups, along with experimental considerations for their application. The review brings together updated examples of functionalities used and places specific emphasis on the analytical techniques used for the determination of deblocking temperature, updating previous reviews with the newly applied technique of X-ray photoelectron spectroscopy (XPS). Additionally, we put forward a brief update on the use of blocked isocyanates for other non-traditional polyurethane based polymer applications. We also highlight the importance of matching the analytical technique to the application of the blocked isocyanate, with differences in material state and experimental parameters having a great impact on the deblocking temperature reported.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Blocked isocyanates: from analytical and experimental considerations to non-polyurethane applications

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