Facile one-pot/one-step synthesis of heterotelechelic N-acylated poly(aminoester) macromonomers for carboxylic acid decorated comb polymers

文献情報

出版日 2016-10-19

DOI 10.1039/C6PY01553K

インパクトファクター 5.582

著者

Patrick A. J. M. de Jongh, Mechelle R. Bennett, Greg S. Sulley

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要旨

Optimised monomer feed ratios in the spontaneous zwitterionic copolymerisation (SZWIP) of 2-oxazolines and acrylic acid enable the one-step synthesis of heterotelechelic α-acrylate, ω-carboxylic acid N-acylated poly(aminoester) macromonomers. Subsequent redox-initiated RAFT polymerisation at ambient temperature leads to comb polymers containing quantitative terminal side chain carboxylic acids, which allow efficient ‘grafting-onto’ using conventional peptide coupling strategies.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Facile one-pot/one-step synthesis of heterotelechelic N-acylated poly(aminoester) macromonomers for carboxylic acid decorated comb polymers

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