ADMET and TAD chemistry: a sustainable alliance

文献情報

出版日 2016-08-16

DOI 10.1039/C6PY01144F

インパクトファクター 5.582

著者

L. Vlaminck, K. De Bruycker, O. Türünç, F. E. Du Prez

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要旨

A versatile, additive-free post-polymerisation functionalisation method for acyclic diene metathesis (ADMET) derived polymers, utilising 1,2,4-triazoline-3,5-dione (TAD) chemistry, is reported. Several diene monomers have been synthesised starting from 10-undecenoic acid derivatives and subsequently polymerised via ADMET polymerisation reaction. Post-polymerisation functionalisation of the poly-unsaturated macromolecules with several substituted TAD compounds was shown to achieve full conversions within 6 hours. Also, the functionalised polymers could be chemically crosslinked with a bivalent triazolinedione crosslinker. The glass transition temperature of the resulting materials could be tuned by varying the degree of functionalisation, the polymer backbone, the TAD substituent and the crosslinking density.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

ADMET and TAD chemistry: a sustainable alliance

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