The reactivity of platinum microelectrodes
文献情報
Leon Jacobse, Stefan J. Raaijman, Marc T. M. Koper
Despite the widespread application of ultramicroelectrodes (UMEs), the customary method of their electrochemical characterization via outer sphere redox probing has serious limitations. In this study we provide additional insights into this subject by measuring not only outer sphere redox couples, but also blank voltammetries and the reactivity towards various catalytic reactions of Pt UMEs. The data for the UMEs are compared to those for macroscale Pt electrodes that can be flame-annealed. Although the reactivity is similar for reactions that are rather insensitive to the surface structure (and/or composition), UMEs perform much worse for more surface sensitive catalytic reactions. This effect can be explained by the UMEs being contaminated much faster, though it remains to be established if the origin of this contamination lies in the preparation method or in the impurities in the (high-purity grade) chemicals used. Our study recommends that catalytic reactivity measurements on ultramicroelectrodes should always be accompanied by blank voltammetries and the results have to be interpreted extremely carefully.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.












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