The 3D [(Cu2Br2){μ-EtS(CH2)4SEt}]n material: a rare example of a coordination polymer exhibiting triplet–triplet annihilation

文献情報

出版日 2016-08-25

DOI 10.1039/C6CP04728A

インパクトファクター 3.676

著者

Antoine Bonnot, Paul-Ludovic Karsenti, Frank Juvenal, Christopher Golz, Carsten Strohmann, Daniel Fortin, Michael Knorr, Pierre D. Harvey

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要旨

EtS(CH2)4SEt, L1, forms with CuI a luminescent 2D polymer [Cu4I4{μ-L1}2]n (CP1), which exhibits no triplet excitation energy migration, but with CuBr, it forms a 3D material (CP2), [(Cu2Br2){μ-L1}]n consisting of parallel (Cu2Br2S2)n layers bridged by L1's. CP2 shows T1–T1 annihilation at 298 K but not at 77 K.

掲載誌

Physical Chemistry Chemical Physics

CiteScore: 5.5

自己引用率: 10.3%

年間論文数: 3036

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