Metallic cyanoacetylides of copper, silver and gold: generation and structural characterization
文献情報
Carlos Cabezas, Carmen Barrientos, Antonio Largo, Jean-Claude Guillemin, J. L. Alonso
The metallic cyanoacetylides CuCCCN, AgCCCN, and AuCCCN have been synthesized in the throat of a pulsed supersonic expansion by reaction of metal vapors, produced by laser ablation, and BrCCCN. Their pure rotational spectra in the (X1Σ+) electronic ground state were observed by Fourier transform microwave spectroscopy in the 2–10 GHz frequency region. Importantly, the rotational spectroscopy constants determined from the analysis of the rotational spectra clearly established the existence of metal–CCCN arrangements for all the mentioned cyanoacetylides. A study of the chemical bonding by means of a topological analysis of the electron density helps to understand the preference for metal–C bonding over metal–N bonding.
関連文献
Sorption enhanced CO2 methanation
Andreas Borgschulte, Noris Gallandat, Benjamin Probst, Riccardo Suter, Elsa Callini, Davide Ferri, Yadira Arroyo, Rolf Erni, Hans Geerlings, Andreas Züttel
DOI: 10.1039/C3CP51408K
Large excited state two photon absorptions in the near infrared region of surprisingly stable radical cations of (ferrocenyl)indenes
Laura Orian, Stefano Scuppa, Saverio Santi, Moreno Meneghetti
DOI: 10.1039/C3CP51257F
Green synthesis of TiO2nanocrystals with improved photocatalytic activity by ionic-liquid assisted hydrothermal method
Lingju Guo, Meng He, Tao He
DOI: 10.1039/C3CP50862E
Hydrogenolysis of ethylene glycol to methanol over modified RANEY® catalysts
Cheng-Tar Wu, Jin Qu, Joseph Elliott, Kai Man Kerry Yu, Shik Chi Edman Tsang
DOI: 10.1039/C3CP51619A
Complex three-dimensional polymer–metal core–shell structures towards emission control
De-Gong Wang, Li-Gang Niu, Bin-Bin Xu, Jun-Feng Song, Qi-Dai Chen, Hong-Bo Sun
DOI: 10.1039/C3CP44051F
Stepping stones in the electron transport from cells to electrodes in Geobacter sulfurreducens biofilms
Pablo Sebastián Bonanni, Diego Massazza, Juan Pablo Busalmen
DOI: 10.1039/C3CP50411E
Highly-efficient charge separation and polaron delocalization in polymer–fullerene bulk-heterojunctions: a comparative multi-frequency EPR and DFT study
Jens Niklas, Kristy L. Mardis, Brian P. Banks, Gregory M. Grooms, Andreas Sperlich, Vladimir Dyakonov, Serge Beaupré, Mario Leclerc, Tao Xu, Luping Yu, Oleg G. Poluektov
DOI: 10.1039/C3CP51477C
The effect of dimensionality of nanostructured carbon on the architecture of organic–inorganic hybrid materials
R. D. K. Misra, D. Depan, J. Shah
DOI: 10.1039/C3CP51236C
Structural and electronic properties of Li8ZrO6 and its CO2 capture capabilities: an ab initio thermodynamic approach
Yuhua Duan
DOI: 10.1039/C3CP51101D
こちらもおすすめ
(S)-四氢呋喃-3-羧酸の物理化学的性質は何ですか?
CAS番号168395-26-4の(S)-四氢呋喃-3-羧酸は、白色の結晶が特徴的な性質を持ちます。分子量は128.08であり、水に溶けやすく、アルコールなど...
塩基性硫黄化合物1,3-ジメチル-1-[5-(三氟甲基)-1,3,4-硫杂环己二酮-2-基]尿素を含む廃棄物はどのように処理すべきですか?
塩基性硫黄化合物1,3-ジメチル-1-[5-(三氟甲基)-1,3,4-硫杂环己二酮-2-基]尿素を含む廃棄物は、専門的な廃棄処理施設で焼却処理を行うべきです。ま...
インドリジン-2-カルボン酸は安全ですか?
インドリジン-2-カルボン酸は一般的に安全ですが、過度に濃い状態では刺激性があります。取り扱いには適切な防護具を使用し、直接触れや吸入を避ける必要があります。
5-甲基-2-(3-ピリジニル)-1,3-テイゾール-4-オールの市場動向や研究トレンドはどうですか?
5-甲基-2-(3-ピリジニル)-1,3-テイゾール-4-オールは、医薬品や農薬、および合成化学の分野において研究が進められています。市場動向としては、化学物質...
4,4',4''-(嘧啶-2,4,6-三基)三苯甲醛はどのように保存すればよいですか?
4,4',4''-(嘧啶-2,4,6-三基)三苯甲醛は、密閉容器に保管し、避けておくことが重要です。室温で保管し、直射日光を避けてください。
(3aR)-1,3,3-トリフェニルテトラヒドロ-3H-ピロロ[1,2-c][1,3,2]-オキザボロロールについて、適用される法規ガイドラインは何ですか?
(3aR)-1,3,3-トリフェニルテトラヒドロ-3H-ピロロ[1,2-c][1,3,2]-オキザボロロールは、GHS(国際危険物識別ルール)の分類が適用されま...
6-(4-氯苯氧基)吡啶-3-胺の代替品はありますか?
6-(4-氯苯氧基)吡啶-3-胺の代替品としては、他の芳香族アミン化合物や類似の除草剤が考えられます。ただし、他の化合物と同様に、代替品の選択には安全性と効果性...
3-フェニル-3,4-ジヒドロ-2H-1,4-ベンゾキサジンを取り扱う際の実験室安全事項は何ですか?
3-フェニル-3,4-ジヒドロ-2H-1,4-ベンゾキサジンを取り扱う際は、防塵マスク、ゴーグル、ゴム手袋を使用し、ドラフトチャンバー内で作業することを推奨しま...
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










![[2-(Benzyloxy)-3-bromo-5-methylphenyl]boronic acid structure [2-(Benzyloxy)-3-bromo-5-methylphenyl]boronic acid structure](https://static.chemtradehub.com/structs/870/870777-20-1-24ac.webp)



![9H-Fluoren-9-ylmethyl [(2S)-1-hydroxy-3-(1H-indol-3-yl)-2-propanyl]carbamate structure 9H-Fluoren-9-ylmethyl [(2S)-1-hydroxy-3-(1H-indol-3-yl)-2-propanyl]carbamate structure](https://static.chemtradehub.com/structs/153/153815-60-2-a67d.webp)