Influence of the mixed organic cation ratio in lead iodide based perovskite on the performance of solar cells
文献情報
Manuel Salado, Laura Calio, Rüdiger Berger, Samrana Kazim, Shahzada Ahmad
Lead halide based perovskite solar cells are presently the flagship among the third generation solution-processed photovoltaic technologies. The organic cation part in the perovskite plays an important role in terms of crystal structure tuning from tetragonal to trigonal or pseudocubic or vice versa depending on the organic cations used, while it also displays different microstructure. In this paper, we demonstrate the influence of the organic cation part with respect to optical properties, hysteresis behavior, and stability. This study offers a clear understanding of the perovskite properties and how they can be modulated by compositional engineering. With a rational choice, light harvesting abilities and hysteresis behavior can be controlled in these systems. The substitution of formamidinium cation by methylammonium cation allows achieving low temperature annealing and inducing stability in perovskites together with enhanced photovoltaic properties. By the use of in-situ scanning force microscopy experiments the conversion of precursors to perovskite at a particular temperature can be visualized.
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.
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