Pd(ii)-catalyzed β-C–H arylation of O-methyl ketoximes with iodoarenes

文献情報

出版日 2016-01-21

DOI 10.1039/C5QO00438A

インパクトファクター 5.281

著者

Yucheng Mu, Yemin Zhang, Xiaobi Jing, Zhuangzhi Shi

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要旨

A Pd(II)-catalyzed selective β-arylation of O-methyl ketoximes was developed using iodoarenes as the coupling partners. This transformation has good functional group compatibility and can serve as a powerful synthetic tool for late-stage C–H arylation of complex compounds. Moreover, when employing 2-iodobenzoic acids as the substrates in this developed catalytic system, a type of unexpected five-membered lactones could be formed by tandem sp3 C–H arylation and oxygenation.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Pd(ii)-catalyzed β-C–H arylation of O-methyl ketoximes with iodoarenes

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