Exploiting ortho-substitution effect on formation of oxygen-containing [10]paracyclophane through ring-closing metathesis

文献情報

出版日 2015-12-22

DOI 10.1039/C5QO00373C

インパクトファクター 5.281

著者

Li Yang, Liqiang Song, Chong Huang, Mingzheng Huang, Bo Liu

原文を見る

要旨

The synthesis of strained paracyclophanes is challenging and generally delivers low yields. A novel strategy of installing an ortho-substituent group to the ethereal oxygen is developed to facilitate the formation of oxygen-containing [10]paracyclophane via RCM macrocyclization. By rationally modulating the electronic and steric effects in the single and double ortho-substitution modes, efficient RCM macrocyclization was achieved for different substrates to form the corresponding [10]paracyclophane products, in which all newly generated double bonds were in the E-form. The development of this methodology will enrich the chemistry of ring-closing metathesis related to the formation of strained macrocycles.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Exploiting ortho-substitution effect on formation of oxygen-containing [10]paracyclophane through ring-closing metathesis

文献情報

おすすめジャーナル

関連文献

Enhanced performance for organic bulk heterojunction solar cells by cooperative assembly of ter(ethylene oxide) pendants

Contents list

Engineering the band gap and energy level of conjugated polymers using a second acceptor unit

Front cover

High performance polymer solar cells based on a two dimensional conjugated polymer from alkylthienyl-substituted benzodifuran and benzothiadiazole

Synthesis of triphenylamine based polysiloxane as a blue phosphorescent host

Synthesis of 3-, 4-, 5-, 6-, 7-, 8-, 9-, 10-, 11-, and 12-armed star-shaped poly(styrene oxide) Ru(ii) complexes by a click-to-chelate approach

Immortal ring-opening polymerization of ε-caprolactone by a neat magnesium catalyst system: an approach to obtain block and amphiphilic star polymers in situ

Facile fabrication of reduction-responsive nanocarriers for controlled drug release

Efficient and economical synthesis of dendrimer-like polystyrene with long subchains through arm-first divergent strategy

こちらもおすすめ

1-{3-[5-(エチルカルボンイル)-2,4-ジメチル-1H-ピロロール-3-基]プロパニル}ピペリジン-4-カルボン酸について、適用される法規ガイドラインは何ですか？

2,2-二氟-1,3-ベンゾジオキサン-5-カルボキシlic酸とは何ですか？

8-氯-4-色原酮の代替品はありますか？

エチル6,6-ジメチル-4,5,6,7-テトラヒドロ-1H-インドアゼー-3-カルボキシレートとは何ですか？

4-叔丁基-6-氯-嘧啶に適用される法規ガイドラインは何ですか？

維库溴铵杂质Bはどのように合成されますか？

2-(4-氟苄基)-吡咯烷の物理化学的性質は何ですか？

3-喹啉甲醛（2-チロール-8-エチル）は安全ですか？

エチル3-(ヒドロキシメチル)-1H-ピロール-2-カルボキシレートはどのように保存すればよいですか？

哌拉西林杂质Dは安全ですか？

掲載誌

Organic Chemistry Frontiers

おすすめ化合物

4-Ethyl-2-methoxyphenol

2-Methyl-2-propanyl (2-aminoethyl)carbamate

Methyl 4-chloro-2-pyridinecarboxylate

Danthron (1,8-Dihydroxyanthraquinone)

6-Methyl-3-pyridinamine

おすすめサプライヤー