Open-cage fullerene with a stopper acts as a molecular vial for a single water molecule

文献情報

出版日 2015-09-10

DOI 10.1039/C5QO00265F

インパクトファクター 5.281

著者

Liang Xu, Sisi Liang, Jiahao Sun

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要旨

An open-cage fullerene derivative with three carbonyl groups on the rim of the orifice reacts with o-diaminobenzene reversibly to form a tetrahydrofuran moiety above the orifice. Water encapsulation and release experiments show that the tetrahydrofuran moiety acts as a stopper effectively blocking the orifice. The addition and removal of o-diaminobenzene serve as a chemically controlled switching process for the fullerene-based water container, which is suited for just one water molecule due to its moderate cavity size.

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Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Open-cage fullerene with a stopper acts as a molecular vial for a single water molecule

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