Polyethylene glycol-400/H3PO2: an eco-friendly reductive system for the synthesis of selanylesters

文献情報

出版日 2015-09-21

DOI 10.1039/C5QO00256G

インパクトファクター 5.281

著者

G. Perin, M. B. Silveira, A. M. Barcellos, R. G. Jacob, D. Alves

原文を見る

要旨

An alternative green method was described for the synthesis of selanylesters by reactions of acyl chlorides with arylselenols, generated in situ by reaction of diaryl diselenides with hypophosphorous acid (H3PO2) using polyethylene glycol-400 (PEG-400) as the solvent. These reactions proceeded efficiently at room temperature under N2 using a range of acyl chlorides and diaryl diselenides, both containing electron-withdrawing and electron-donating groups, affording the corresponding selanylesters in moderate to excellent yields. Additionally, PEG-400 can be recovered and directly reused for further reactions.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Polyethylene glycol-400/H3PO2: an eco-friendly reductive system for the synthesis of selanylesters

文献情報

おすすめジャーナル

関連文献

Hydantoin hexameric rosettes: harnessing H-bonds for supergelation and liquid crystals

Chalcogen bonding enabled photosynthesis of aryl selenides from aryl sulfonium salts

B(C6F5)3-catalyzed stepwise 1,5-hydride migration/cyclization: diastereoselective construction of carbocyclic β-amino acid derivatives

A catalyst-free cross-coupling of isocyanates and triarylboranes for secondary amide synthesis

Halogen bonding and mechanochemistry combined: synthesis, characterization, and application of N-iodosaccharin pyridine complexes

Using pyrrolizine-fused bipolar PAHs as a new strategy towards efficient red and NIR emissive dyes

A novel three-component coupling reaction of aryne, CN derivatives, and acrylonitrile

Correction: A facile, one-pot reductive alkylation of aromatic and heteroaromatic amines in aqueous micellar media: a chemoenzymatic approach

N-heterocyclic nitrenium charge transfer catalysis via inner-sphere electron transfer in concert with halogen-atom dissociation

Photocatalytic decarboxylative phosphorylation of N-aryl glycines

こちらもおすすめ

6-苄基-6,7-二氢-5H-吡咯并3,4-b吡啶とは何ですか？

半硫酸奎宁单水水合物はどのように保存すればよいですか？

D-核糖-5-リン酸二ナトリウムとは何ですか？

異丙基肼はどの業界で使用されていますか？

3-乙酰基-4-羟基喹啉-2(1H)-酮はどのように合成されますか？

Bobcat339はどのように保存すればよいですか？

5-溴-4-甲基-1H-吲唑とは何ですか？

3-(4メトキシフェニル)オキテナン-3カーボイル酸の代替品はありますか？

3-イリドオキシピロロ[2,3-b]ピリジン-5-カルボキシlic酸は安全ですか？

3-氟-4- iodobenolを取り扱う際の実験室安全事項は何ですか？

掲載誌

Organic Chemistry Frontiers

おすすめ化合物

tert-Butyl 6-chloro-4-oxospiro[chroman-2,4'-piperidine]-1'-carboxylate

Abacavir 5’-Phosphate

4-Chloro-2-{[(2-chlorophenoxy)acetyl]amino}benzoic acid

1-(3,4-Dichlorophenyl)-1H-pyrazole-3-carboxylic acid

1-(4-tert-Butylphenyl)ethanol

おすすめサプライヤー