Alkynyl trifluoromethyl selenide synthesis via oxidative trifluoromethylselenolation of terminal alkynes

文献情報

出版日 2015-03-30

DOI 10.1039/C5QO00045A

インパクトファクター 5.281

著者

Yuguang Wang, Yi You, Zhiqiang Weng

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要旨

The synthesis of alkynyl trifluoromethyl selenides by Cu-mediated oxidative trifluoromethylselenolation of terminal alkynes is reported. Treatment of [(bpy)Cu(SeCF3)]2 with various terminal alkynes in the presence of an oxidant, Dess–Martin periodinane, led to the formation of trifluoromethylselenolated acetylenes bearing sensitive moieties such as alkoxy, halogens, trifluoromethyl, and heterocyclic groups.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Alkynyl trifluoromethyl selenide synthesis via oxidative trifluoromethylselenolation of terminal alkynes

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