α-(Aminomethyl)acrylate: polymerization and spontaneous post-polymerization modification of β-amino acid ester for a pH/temperature-responsive material

文献情報

出版日 2015-06-16

DOI 10.1039/C5PY00723B

インパクトファクター 5.582

著者

Yasuhiro Kohsaka, Yusuke Matsumoto, Tatsuki Kitayama

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要旨

Ethyl α-(aminomethyl)acrylate, a β-amino acid ester carrying a conjugated vinylidene group at the α-position, was radically polymerized. The polymerization was found to involve subsequent ester–amide exchange reaction between the amino pendants of the polymer and an ester group of the monomer, affording acrylamide-bearing units in 11–15% contents. The obtained polymer exhibited pH/temperature responsiveness in aqueous media.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

α-(Aminomethyl)acrylate: polymerization and spontaneous post-polymerization modification of β-amino acid ester for a pH/temperature-responsive material

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