Dual side chain control in the synthesis of novel sequence-defined oligomers through the Ugi four-component reaction

文献情報

出版日 2015-03-24

DOI 10.1039/C5PY00424A

インパクトファクター 5.582

著者

Susanne C. Solleder, Katharina S. Wetzel, Michael A. R. Meier

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要旨

The synthesis of sequence-defined oligomers by the iterative application of the modular Ugi four-component reaction (U-4CR) and the efficient thiol–ene addition reaction is described. By varying the amine component in the U-4CR, a sequence-defined and monodisperse tetramer (M = 1568.5 g mol−1) was obtained. More interestingly, if both the amine and the isocyanide components were varied simultaneously in the U-4CR, a double sequence-controlled, monodisperse pentamer (M = 2411.8 g mol−1) bearing ten different and selectable side chains was obtained. All oligomers were thoroughly characterized by NMR and IR spectroscopy, mass spectrometry and GPC.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Dual side chain control in the synthesis of novel sequence-defined oligomers through the Ugi four-component reaction

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