Soluble, microporous ladder polymers formed by stepwise nucleophilic substitution of octafluorocyclopentene

文献情報

出版日 2015-05-01

DOI 10.1039/C5PY00359H

インパクトファクター 5.582

著者

Krishnan Ranganathan, Parthiban Anbanandam

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要旨

Octafluorocyclopentene (OFCP) has been demonstrated as a non-aromatic tetrafunctional monomer suitable for making soluble ladder polymers of intrinsic microporosity. Ladder polymers with a varying surface area were prepared by reacting one mole of OFCP with 2 moles of bisphenols of the same or different types. BET analysis of ladder polymers indicated that the surface area formed is comparable to that of microporous polymers derived from polyimides. MALDI-TOF MS indicated the presence of one OFCP and two bisphenol moieties in every repeating unit thereby confirming the presence of ladders in the polymer backbone.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

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Soluble, microporous ladder polymers formed by stepwise nucleophilic substitution of octafluorocyclopentene

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