Stereoregular poly(methyl methacrylate) with double-clickable ω-end: synthesis and click reaction

文献情報

出版日 2015-04-14

DOI 10.1039/C5PY00357A

インパクトファクター 5.582

著者

Yasuhiro Kohsaka, Kazuki Yamamoto, Tatsuki Kitayama

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要旨

Isotactic and syndiotactic poly(methyl methacrylate)s with orthogonally double-clickable terminal ends, that is, α,β-unsaturated esters for Michael addition-type thiol–ene reactions and azide or alkynyl groups for azide–alkyne click reactions, were prepared via a terminating reaction of stereospecific anionic polymerization with propargyl and 2-chloroethyl α-(chloromethyl)acrylates. The subsequent polymer modification via a double click reaction proceeded quantitatively in a one-pot system under ambient conditions. The facile and almost quantitative double-end-functionalization would open a new material design based on stereoregular PMMAs with controlled molecular weights.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Stereoregular poly(methyl methacrylate) with double-clickable ω-end: synthesis and click reaction

文献情報

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Polymer Chemistry

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