Wavelength resolved specific optical rotations and homochiral equilibria
文献情報
P. L. Polavarapu, C. L. Covington
The fundamental expressions governing specific optical rotations (SORs) of homochiral systems exhibiting monomer–dimer equilibria are presented. These equations are then utilized with the experimental measurements of wavelength resolved circular birefringence for (R)-(−)-α-hydroxy-β,β-dimethyl-γ-butyrolactone, to determine the wavelength resolved SORs of monomer and dimer components for the first time. Density functional theory predictions on the corresponding dispersion properties of monomer and dimer are found to match with experimentally determined quantities within a factor of ∼2. The wavelength resolved circular birefringence in the liquid solution phase thus provides a powerful means to investigate the molecular properties involved in homochiral equilibria.
おすすめジャーナル

Journal of Heterocyclic Chemistry

Organic Preparations and Procedures International

Nature

European Journal of Wood and Wood Products

Journal of Organometallic Chemistry

Israel Journal of Chemistry

Planta Medica

Helvetica Chimica Acta

Journal of Catalysis

Proceedings of the National Academy of Sciences of the United States of America
関連文献
Mechanism of gas-phase ozonolysis of sabinene in the atmosphere
DOI: 10.1039/C7CP03216A
The role of phonon–phonon and electron–phonon scattering in thermal transport in PdCoO2
Long Cheng, Qing-Bo Yan
DOI: 10.1039/C7CP03667A
A molecular dynamics study of conformations of beta-cyclodextrin and its eight derivatives in four different solvents
Mikko Karttunen
DOI: 10.1039/C7CP04009A
Photoinduced dynamics of the hole-transport material H101 in organic solvents and on mesoporous Al2O3 and TiO2 thin films
Johannes R. Klein, Mirko Scholz, Kawon Oum, Thomas Lenzer
DOI: 10.1039/C7CP01718A
Evidence for coherent mixing of excited and charge-transfer states in the major plant light-harvesting antenna, LHCII
Charusheela Ramanan, Marco Ferretti, Henny van Roon, Vladimir I. Novoderezhkin, Rienk van Grondelle
DOI: 10.1039/C7CP03038J
Photoexcitation dynamics of p-nitroaniline and N,N-dimethyl-p-nitroaniline in 1-alkyl-3-methylimidazolium-cation based ionic liquids with different alkyl-chain lengths
Y. Kimura, S. Ibaraki, R. Hirano, Y. Sugita, Y. Yasaka, M. Ueno
DOI: 10.1039/C7CP03610H
Tuning the gap of lead-based halide perovskites by introducing superalkali species at the cationic sites of ABX3-type structure
C. Paduani, Andrew M. Rappe
DOI: 10.1039/C7CP02091K
Reply to comment on “Brownian diffusion of a particle at an air/liquid interface: elastic (not viscous) response of the surface”
Jhoan Toro-Mendoza, Gieberth Rodriguez-Lopez, Oscar Paredes-Altuve
DOI: 10.1039/C7CP04415A
こちらもおすすめ
3-(2-オキサプロピル)ベンzoic酸はどのように合成されますか?
3-(2-オキサプロピル)ベンzoic酸は、ベンzoic酸とプロパノ酸をヒドロキシム化合物として反応させて生成します。具体的には、ベンzoic酸とプロパノ酸を反...
4-メチル-4-ピペリジニル-1-ピロリドイン甲酸の主な用途は何ですか?
4-メチル-4-ピペリジニル-1-ピロリドイン甲酸は、主に医薬品の合成材料や研究用物質として使用されます。さらに、一部の薬理学的研究にも応用されています。
Biotin-PEG3-oxyamine HCl塩について、適切な化合物名称に適用される法規ガイドラインは何ですか?
Biotin-PEG3-oxyamine HCl塩は、GHS( Globally Harmonized System of Classification and...
N-(4-イソチオシアネートフェニル)-2-メトキシアリニンはどのように合成されますか?
N-(4-イソチオシアネートフェニル)-2-メトキシアリニンは、4-イソチオシアノフェノールと2-メトキシアリニルアミンのアミニド反応を用いて合成されます。この...
金粉蕨亭2'-O-葡萄糖甙の主な用途は何ですか?
金粉蕨亭2'-O-葡萄糖甙は主に薬理研究や医薬品製造に使用され、抗炎症作用や抗がん作用などがあります。また、その構造や性質から、合成化学や化学生理学の研究にも用...
2-(2-ニトロフェニル)酢酸ヒドライドの物理化学的性質は何ですか?
2-(2-ニトロフェニル)酢酸ヒドライドのCAS番号は114953-81-0です。この化合物は白色結晶性粉末で、分子量は244.12です。水溶性は限られており、...
5-(ヒドロキシメチル)-2-チオキソ-2,3-ジヒドロピリミジン-4(1H)-オンを取り扱う際の実験室安全事項は何ですか?
この化合物は高活性のため、取り扱いには注意が必要です。PPE(個人保護具)としてゴーグル、ガントリー、および防滴シールドを着用することが推奨されます。ドラフトチ...
11-脱氢血栓烷 b2の市場動向や研究トレンドはどうですか?
11-脱氢血栓烷 b2は、血栓溶解・抗凝固作用に関する研究で注目を集めています。特に心血管疾患の治療法開発において、市場の需要が高まっています。研究トレンドとし...
3,3-二甲基哌啶-4-酮はどのように保存すればよいですか?
3,3-二甲基哌啶-4-酮は避光、常温、乾燥した場所で保存してください。容器は密閉し、遠くから火源を離して保管することを確認してください。
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.


![1-Benzyl-1,7-diazaspiro[4.4]nonane dihydrochloride structure 1-Benzyl-1,7-diazaspiro[4.4]nonane dihydrochloride structure](https://static.chemtradehub.com/structs/115/1159822-71-5-0320.webp)

