Synthesis and characterization of quaternary phosphonium-containing, trithiocarbonate RAFT agents

文献情報

出版日 2014-06-27

DOI 10.1039/C4PY00615A

インパクトファクター 5.582

著者

Longhe Zhang, Qiang Tang, R. A. Weiss, Kevin A. Cavicchi

原文を見る

要旨

In this article the syntheses of quaternary phosphonium-containing trithiocarbonate RAFT agents (RAFT-PR3, R = Bu and Ph) and their use in the bulk, thermally initiated polymerization of styrene were examined. It was found that the thermal stabilities of RAFT-PR3 were enhanced compared to comparable quaternary ammonium-containing RAFT agents, which significantly improved the retention of the cationic end-functionality of the polystyrene obtained by high temperature bulk polymerization. The crude polystyrene was further purified via column chromatography to yield high purity hemi-telechelic polystyrene cationomers.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Synthesis and characterization of quaternary phosphonium-containing, trithiocarbonate RAFT agents

文献情報

おすすめジャーナル

関連文献

Group 13 five- and six-membered rings with rare 2π aromaticity

Simultaneous organic carbon, nitrogen removal, and electricity generation in a novel A4-MFC system for the treatment of leachate from a composting site: performance and modeling

Effects of gamma radiation on the electrical properties of InAs/InGaAs quantum dot-based laser structures grown on GaAs and Si substrates by molecular beam epitaxy

Simulation of exciton spectra in disordered supramolecular polymers: exciton localization in cisoid indolenine squaraine hexamers

Towards the thermal stability of dye-sensitized solar cells for wavelength-selective greenhouses using the polymorphism of light-scattering layers

Theoretical design of durable and strong polycarbonates against photodegradation

Performance optimization of a thermoelectric generator for automotive application using an improved whale optimization algorithm

An iron phosphate hydroxide hydrate electrocatalyst: synergistic effects of Fe2+ and Fe3+ for enhanced hydrogen evolution reaction stability

Differential effects of MoO3 and MoO2 sacrificial layers on the J–V performance of Cu2ZnSn(S,Se)4 solar cells

Back cover

こちらもおすすめ

1-{3-[5-(エチルカルボンイル)-2,4-ジメチル-1H-ピロロール-3-基]プロパニル}ピペリジン-4-カルボン酸について、適用される法規ガイドラインは何ですか？

2,2-二氟-1,3-ベンゾジオキサン-5-カルボキシlic酸とは何ですか？

8-氯-4-色原酮の代替品はありますか？

エチル6,6-ジメチル-4,5,6,7-テトラヒドロ-1H-インドアゼー-3-カルボキシレートとは何ですか？

4-叔丁基-6-氯-嘧啶に適用される法規ガイドラインは何ですか？

維库溴铵杂质Bはどのように合成されますか？

2-(4-氟苄基)-吡咯烷の物理化学的性質は何ですか？

3-喹啉甲醛（2-チロール-8-エチル）は安全ですか？

エチル3-(ヒドロキシメチル)-1H-ピロール-2-カルボキシレートはどのように保存すればよいですか？

哌拉西林杂质Dは安全ですか？

掲載誌

Polymer Chemistry

おすすめ化合物

Pimecrolimus

3-Bromophenylboronic acid

Glycol salicylate

Diphenyl hydrogen phosphate

2-Bromodibenzo[b,d]furan

おすすめサプライヤー