Synthesis and self-assembly of a novel fluorinated triphilic block copolymer

文献情報

出版日 2014-04-22

DOI 10.1039/C4PY00308J

インパクトファクター 5.582

著者

Xinxin Li, Yanhua Yang, Guojun Li

原文を見る

要旨

A novel fluorinated diblock tercopolymer was synthesized by the reversible addition fragmentation chain transfer method, incorporating methacrylic acid, methyl methacrylate, and perfluoroalkyl ethyl methylacrylate blocks as hydrophilic, lipophilic, and fluorophilic units, respectively. Depending upon the specific triphilic balance, under control solution conditions, the block copolymer self-assembled in dimethylformamide/water dispersions induced an evolution from spheres to wormlike structures, and finally to novel nail-shaped structures, as verified by transmission electron microscopy and dynamic light scattering. The control mechanism is explained in terms of the effect of each property on the forces that govern the formation of any given morphology, namely the core-chain stretching, strong incompatibility between the lipophilic blocks and the fluorophilic blocks, and interfacial tension.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Synthesis and self-assembly of a novel fluorinated triphilic block copolymer

文献情報

おすすめジャーナル

関連文献

Simulation of exciton spectra in disordered supramolecular polymers: exciton localization in cisoid indolenine squaraine hexamers

Solvent-controlled synthesis of hydrophilic and hydrophobic carbon dots

A self-phosphorized carbon-based monolithic chainmail electrode for high-current-density and durable alkaline water splitting

Polystyrene-based catalysts with simultaneous Brønsted and Lewis acidity for hydroxymethylfurfural production from starch: molecular weight and solvent effects

Effects of gamma radiation on the electrical properties of InAs/InGaAs quantum dot-based laser structures grown on GaAs and Si substrates by molecular beam epitaxy

Research on structural strengthening technology for regenerative denitration catalysts

Design for six sigma-based energy management for a plug-in fuel cell electric bus considering the noise disturbance

An electrospun PVDF-KNN nanofiber based lead-free piezoelectric nanogenerator for mechanical energy scavenging and self-powered force sensing applications

Synthesis of hierarchical MFI zeolite by interzeolite conversion of spent FAU zeolite for the methanol-to-olefins reaction

Towards the thermal stability of dye-sensitized solar cells for wavelength-selective greenhouses using the polymorphism of light-scattering layers

こちらもおすすめ

1-{3-[5-(エチルカルボンイル)-2,4-ジメチル-1H-ピロロール-3-基]プロパニル}ピペリジン-4-カルボン酸について、適用される法規ガイドラインは何ですか？

2,2-二氟-1,3-ベンゾジオキサン-5-カルボキシlic酸とは何ですか？

8-氯-4-色原酮の代替品はありますか？

エチル6,6-ジメチル-4,5,6,7-テトラヒドロ-1H-インドアゼー-3-カルボキシレートとは何ですか？

4-叔丁基-6-氯-嘧啶に適用される法規ガイドラインは何ですか？

維库溴铵杂质Bはどのように合成されますか？

2-(4-氟苄基)-吡咯烷の物理化学的性質は何ですか？

3-喹啉甲醛（2-チロール-8-エチル）は安全ですか？

エチル3-(ヒドロキシメチル)-1H-ピロール-2-カルボキシレートはどのように保存すればよいですか？

哌拉西林杂质Dは安全ですか？

掲載誌

Polymer Chemistry

おすすめ化合物

Hexaflumuron

Sodium methacrylate

Danthron (1,8-Dihydroxyanthraquinone)

Dipotassium 7-hydroxy-1,3-naphthalenedisulfonate

Diphenyl hydrogen phosphate

おすすめサプライヤー