Gated molecular baskets
文献情報
Keith Hermann, Yian Ruan, Alex M. Hardin, Christopher M. Hadad, Jovica D. Badjić
In this review, we describe the construction of gated molecular baskets, discuss their mechanism of action in regulating the exchange of guests and illustrate the potential of these concave hosts to act as catalysts for controlling chemical reactions. Importantly, a number of computational and experimental studies have suggested that gated baskets ought to unfold their gates at the rim for permitting the passage of guests to/from their inner space. These dynamic hosts are therefore offered as useful models for investigating the process of gating in artificial systems. Furthermore, gated baskets should permit examining the benefit of controlling the rate by which reactants access a gated catalyst for promoting chemical reactions occurring in its confined space.
関連文献
Self-assembly and coverage dependent thermally induced conformational changes of Ni(ii)-meso-tetrakis (4-tert-butylphenyl) benzoporphyrin on Cu(111)
DOI: 10.1039/C5CP01490E
Lasing in DNA–CTMA doped with Rhodamine 610 in butanol
T. Bazaru Rujoiu, A. Petris, V. I. Vlad, I. Rau, A.-M. Manea, F. Kajzar
DOI: 10.1039/C5CP01727K
A density functional study of silver clusters on a stepped graphite surface: formation of self-assembled nano-wires
Akansha Singh, Prasenjit Sen
DOI: 10.1039/C5CP01016K
A class of rare antiferromagnetic metallic oxides: double perovskite AMn3V4O12 (A = Na+, Ca2+, and La3+) and the site-selective doping effect
Guangbiao Zhang, Yuanxu Wang, Yuli Yan, Chengxiao Peng, Chao Wang, Shuai Dong
DOI: 10.1039/C5CP00186B
(Hollow Au–Ag nanoparticles)–TiO2 composites for improved photocatalytic activity prepared from block copolymer-stabilized bimetallic nanoparticles
Na Li, Xiaoyu Zhang, Shulong Yuan, Xiaokai Zhang, Yuzhen Yuan, Xue Li
DOI: 10.1039/C4CP06093H
Low temperature (550–700 K) oxidation pathways of cyclic ketones: dominance of HO2-elimination channels yielding conjugated cyclic coproducts
Adam M. Scheer, Oliver Welz, Subith S. Vasu, David L. Osborn, Craig A. Taatjes
DOI: 10.1039/C4CP06097K
Dynamics and mechanisms of DNA repair by photolyase
Zheyun Liu, Lijuan Wang, Dongping Zhong
DOI: 10.1039/C4CP05286B
Three-dimensional sp2-hybridized carbons consisting of orthogonal nanoribbons of graphene and net C
Meng Hu, Xu Dong, Bingchao Yang, Bo Xu, Dongli Yu, Julong He
DOI: 10.1039/C5CP01621E
Robust SiO2-modified CoFe2O4 hollow nanofibers with flexible room temperature magnetic performance
Panpan Jing, Lining Pan, Jinlu Du, Jianbo Wang, Qingfang Liu
DOI: 10.1039/C5CP01228G
Potential-dependent structures investigated at the perchloric acid solution/iodine modified Au(111) interface by electrochemical frequency-modulation atomic force microscopy
Toru Utsunomiya, Shoko Tatsumi, Yasuyuki Yokota, Ken-ichi Fukui
DOI: 10.1039/C5CP01156F
こちらもおすすめ
オステニ二甲磺酸塩に適用される法規ガイドラインは何ですか?
オステニ二甲磺酸塩は、GHS分類に基づき corrosive 物質として分類されます。REACH規則では、該当物質の登録が要求される可能性があります。また、FD...
環丁基肼盐酸盐は安全ですか?
環丁基肼盐酸盐は毒性があり、吸入や皮膚接触は有害です。使用時の安全対策として、密閉システムを使用し、適切な排気設備を備えた場所で作業することが推奨されます。
N-(4-パリドン基ソニルフェニル)硫代イソシアネートを取り扱う際の実験室安全事項は何ですか?
N-(4-パリドン基ソニルフェニル)硫代イソシアネートは高毒性で、皮膚や吸入による毒性があります。取り扱う際は防毒マスク、保護用手袋、保護眼鏡などのPPEを着用...
5-ヒドロキシ-1,3-ジヒドロ-2H-インドン-2-酮の物理化学的性質は何ですか?
CAS番号3416-18-0の5-ヒドロキシ-1,3-ジヒドロ-2H-インドン-2-酮は、結晶性の白色粉末です。分子量は228.25であり、 aqueous m...
O-苄基-D-丝氨醇はどのように合成されますか?
O-苄基-D-丝氨醇は、D-アミノ酸とベンゼン環の経由で合成されます。触媒としてジメチルアミノピリジンが使用され、選択性は高いです。一般的な収率は約90%です。
ナトリウム3-ヒドロキシbutano酸とは何ですか?
ナトリウム3-ヒドロキシbutano酸は、CAS番号13613-65-5で登録されている化合物です。この化合物は、(3R)-3-ヒドロキシbutano酸とナトリ...
1-(二苯甲基)-4-甲基ベンゼンの物理化学的性質は何ですか?
CAS番号603-37-2の1-(二苯甲基)-4-甲基ベンゼンは、結晶性の固体で、分子量は244.28であり、水中的には微溶です。この化合物は有機反応において中...
ネアミン塩酸塩の物理化学的性質は何ですか?
ネアミン塩酸塩の分子量は321.19であり、結晶性の白色粉末です。この化合物は水に溶けやすく、pHが低くなると不溶性になります。反応活性は高く、水溶液中の酸化還...
偶氮二甲酰二哌啶の主な用途は何ですか?
偶氮二甲酰二哌啶は、医薬品、染料、高 Então 剤、触媒、溶媒、量論試薬など、様々な分野で使用されています。特に、高 Enough 反応において、グリコール酸...
掲載誌
Chemical Society Reviews

Chem Soc Rev publishes review articles covering important topics at the forefront of the chemical sciences. Reviews should be of the very highest quality and international impact. We particularly encourage international and multidisciplinary collaborations among our authors. Our scope covers the breadth of the chemical sciences, including interdisciplinary topics where the article has a basis in chemistry. Topics include: Analytical chemistry Biomaterials chemistry Bioorganic/medicinal chemistry Catalysis Chemical Biology Coordination Chemistry Crystal Engineering Energy Sustainable chemistry Green chemistry Inorganic chemistry Inorganic materials Main group chemistry Nanoscience Organic chemistry Organic materials Organometallics Physical chemistry Supramolecular chemistry Synthetic methodology Theoretical and computational chemistry











![4,10-Dihydroxy-3H-pyrano[3,4,5-kl]xanthen-3-one structure 4,10-Dihydroxy-3H-pyrano[3,4,5-kl]xanthen-3-one structure](https://static.chemtradehub.com/structs/125/1259330-61-4-de48.webp)
![2-Methyl-2-propanyl 4-oxo-3,9-diazabicyclo[4.2.1]nonane-9-carboxylate structure 2-Methyl-2-propanyl 4-oxo-3,9-diazabicyclo[4.2.1]nonane-9-carboxylate structure](https://static.chemtradehub.com/structs/131/1312456-05-5-9a15.webp)
