Oxygen nonstoichiometry, the defect equilibrium model and thermodynamic quantities of the Ruddlesden–Popper oxide Sr3Fe2O7−δ
文献情報
Yihan Ling, Fang Wang, Riyan Achmad Budiman, Takashi Nakamura, Koji Amezawa
Oxygen nonstoichiometry of the Ruddlesden–Popper oxide Sr3Fe2O7−δ was measured at intermediate temperatures (773–1073 K) by coulometric titration and high temperature gravimetry. The oxygen nonstoichiometric behavior was analyzed using the defect equilibrium model with localized electrons. From the defect chemical analysis, estimated oxygen vacancy concentration at the O3 sites increases and at the O1 sites decreases with the increasing temperature. This characteristic behavior is considered to be caused by the redistribution of oxygen and vacancies between the O1 and O3 sites. The obtained thermodynamic quantities of the partial molar enthalpy of oxygen, , and the partial molar entropy of oxygen, , calculated from the Gibbs–Helmholtz equation are in good agreement with those from the statistical thermodynamic calculation based on the defect equilibrium model, indicating that the proposed defect equilibrium model is reasonable.
関連文献
Surface species during ALD of platinum observed with in situ reflection IR spectroscopy
Michiel Van Daele, Christophe Detavernier, Jolien Dendooven
DOI: 10.1039/C8CP03585G
Trap state passivation and photoactivation in wide band gap inorganic perovskite semiconductors
Shusheng Pan
DOI: 10.1039/C8CP04298E
Unveiling the role of intra and interatomic interactions in the energetics of reaction schemes: a quantum chemical topology analysis
Jesús Jara-Cortés, Bruno Landeros-Rivera, Jesús Hernández-Trujillo
DOI: 10.1039/C8CP03775B
Systematic analysis of electron energy-loss near-edge structures in Li-ion battery materials
Motofumi Saitoh, Xiang Gao, Takafumi Ogawa, Yumi H. Ikuhara, Shunsuke Kobayashi, Craig A. J. Fisher
DOI: 10.1039/C8CP03390K
An in situ FTIR study of the plasma- and thermally-driven reaction of isopropyl alcohol at CeO2: evidence for a loose transition state involving Ce3+?
P. A. Christensen, Z. T. A. W. Mashhadani, Abd Halim Bin Md Ali, D. A. C. Manning, M. A. Carroll, P. A. Martin
DOI: 10.1039/C8CP05983G
Electrochemical characterisation and comparison of transport in Nafion films and particles
Lifu Chen, Chuhong Lin, Richard G. Compton
DOI: 10.1039/C8CP06504G
Strong and insusceptible photo-emissions from an intramolecular weak hydrogen bond strengthened twisted fluorophore
Binhong Yu, Danyang Liu, Yi Wang, Ting Zhang, Yu-Mo Zhang, Minjie Li, Sean Xiao-An Zhang
DOI: 10.1039/C8CP04242J
こちらもおすすめ
N,N-二乙基-4-ブロモナフサルレン-1-カルボニルアミドはどのように合成されますか?
N,N-二乙基-4-ブロモナフサルレン-1-カルボニルアミドは、4-ブロモナフサルビンとN,N-ジエチルアミド基を有する反応物を用いて合成されます。触媒の使用は...
大黄酚-8-O-葡萄糖苷の市場動向や研究トレンドはどうですか?
大黄酚-8-O-葡萄糖苷の市場は、医薬品、機能食品、研究化学物質としての需要が高まっています。特に、その抗炎症作用や抗ウイルス作用に関する研究が増えています。価...
アトラキュリウム不純物5塩酸塩の物理化学的性質は何ですか?
アトラキュリウム不純物5塩酸塩のCAS番号は2048273-58-9です。この化合物は結晶性であり、分子量は約435.4 g/molです。水に溶けやすく、反応性...
2-イソブチルシクロヘキサン酮とは何ですか?
2-イソブチルシクロヘキサン酮は、CAS番号39207-65-3の化合物で、化学式はC11H20Oです。この化合物は、有機合成化学において重要な原料として使用さ...
2-溴-6-甲基烟酸を取り扱う際の実験室安全事項は何ですか?
この化合物は毒性と刺激性があります。密閉されたドラフトチャンバー内で処理し、PPE(ゴーグル、手袋)を使用してください。漏洩時は即座に通気し、適切な漏洩処理材を...
6-アミノニコニタルデオキシド塩化水和物の物理化学的性質は何ですか?
6-アミノニコニタルデオキシド塩化水和物のCAS番号は1588441-31-9です。この化合物は結晶性粉末で、分子量は220.63 g/molです。水に溶けやす...
塩酸中毒藜碱はどのように合成されますか?
塩酸中毒藜碱は、ピペリジンとピリジンの反応により合成されます。具体的には、ピペリジンとピリジンを反応させ、塩基触媒を使用してピペリジン環内 enters 3-ピ...
Methyl 4-(6-formyl-2-pyridinyl)benzoateに適用される法規ガイドラインは何ですか?
この化合物はCAS番号834884-81-0で、GHS分類では高毒性の危険性を持つと見なされます。REACH規則では登録が求められ、FDA/EPAでは環境、健康...
1-エチynyル-3-(三氟甲氧基)ベンゼンについて「に適用される法規ガイドラインは何ですか」
CAS番号 866683-57-0の1-エチynyル-3-(三氟甲氧基)ベンゼンは、GHS分類では易燃性化学品が該当し、REACH規則では特定の危険性を評価する...
メチル2-ブロモイソニコネートの代替品はありますか?
メチル2-ブロモイソニコネートの代替品には、メチルイソニコネートや他のブロモ化合物が含まれます。これらの代替物は、特定の用途に応じて選択されます。
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










![Disodium (6R,7R)-7-{[(2R)-2-hydroxy-2-phenylacetyl]amino}-8-oxo-3-({[1-(sulfonatomethyl)-1H-tetrazol-5-yl]sulfanyl}methyl)-5-thia-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylate structure Disodium (6R,7R)-7-{[(2R)-2-hydroxy-2-phenylacetyl]amino}-8-oxo-3-({[1-(sulfonatomethyl)-1H-tetrazol-5-yl]sulfanyl}methyl)-5-thia-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylate structure](https://static.chemtradehub.com/structs/612/61270-78-8-6b58.webp)

![2,5-Furandione, dihydro-3-[3-(triethoxysilyl)propyl]- structure 2,5-Furandione, dihydro-3-[3-(triethoxysilyl)propyl]- structure](https://static.chemtradehub.com/structs/936/93642-68-3-3b4b.webp)

