Constrained control landscape for population transfer in a two-level system
文献情報
Katharine Moore Tibbetts, Herschel Rabitz
The growing success of controlling the dynamics of quantum systems has been ascribed to the favorable topology of the quantum control landscape, which represents the physical observable as a function of the control field. The landscape contains no suboptimal trapping extrema when reasonable physical assumptions are satisfied, including that no significant constraints are placed on the control resources. A topic of prime interest is understanding the effects of control field constraints on the apparent landscape topology, as constraints on control resources are inevitable in the laboratory. This work particularly explores the effects of constraining the control field fluence on the topology and features of the control landscape for pure-state population transfer in a two-level system through numerical simulations, where unit probability population transfer in the system is only accessible in the strong coupling regime within the model explored here. With the fluence and three phase variables used for optimization, no local optima are found on the landscape, although saddle features are widespread at low fluence values. Global landscape optima are found to exist at two disconnected regions of the fluence that possess distinct topologies and structures. Broad scale connected optimal level sets are found when the fluence is sufficiently large, while the connectivity is reduced as the fluence becomes more constrained. These results suggest that seeking optimal fields with constrained fluence or other resources may encounter complex landscape features, calling for sophisticated algorithms that can efficiently find optimal controls.
関連文献
Understanding the influence of Mg doping for the stabilization of capacity and higher discharge voltage of Li- and Mn-rich cathodes for Li-ion batteries
Prasant Kumar Nayak, Judith Grinblat, Elena Levi, Mikhael Levi, Boris Markovsky, Doron Aurbach
DOI: 10.1039/C6CP07383B
Molecular dynamics simulations of the effect of waviness and agglomeration of CNTs on interface strength of thermoset nanocomposites
A. R. Alian, S. A. Meguid
DOI: 10.1039/C6CP07464B
Investigations on Zr incorporation into Li3V2(PO4)3/C cathode materials for lithium ion batteries
Hua-Bin Sun, Ying-Xian Zhou, Lu-Lu Zhang, Xue-Lin Yang, Xing-Zhong Cao, Hanu Arave, Hui Fang, Gan Liang
DOI: 10.1039/C6CP07760A
Adsorbing the 3d-transition metal atoms to effectively modulate the electronic and magnetic behaviors of zigzag SiC nanoribbons
Hui Li, Wei Chen, Xiaopeng Shen, Jingwei Liu, Xuri Huang, Guangtao Yu
DOI: 10.1039/C6CP06717D
A cationic naphthyl derivative defies the non-equilibrated excited rotamers principle
A. Cesaretti, B. Carlotti, F. Elisei, C. G. Fortuna, G. Consiglio, A. Spalletti
DOI: 10.1039/C6CP08311K
Nonadiabatic Renner–Teller quantum dynamics of OH(X2Π) + H+ reactive collisions
Pablo Gamallo, Sinan Akpinar, Paolo Defazio, Carlo Petrongolo
DOI: 10.1039/C6CP07756K
The decomposition of benzenesulfonyl azide: a matrix isolation and computational study
Guohai Deng, Xuelin Dong, Qifan Liu, Dingqing Li, Hongmin Li, Qiao Sun, Xiaoqing Zeng
DOI: 10.1039/C6CP08125H
こちらもおすすめ
2-ブロモ-9,9-ジフェニル-9H-フルオレンの主な用途は何ですか?
2-溴-9,9-二苯基芴は、医薬品、工業材料、有機合成の研究分野で応用されます。特に、レーザー材料や機能性ポリマーの合成に使用されることがあります。また、蛍光色...
四氯化铱の市場動向や研究トレンドはどうですか?
四氯化铱の市場は研究開発分野で注目されており、特にナノ技術や金属有機框架(MOFs)の分野での需要が増加傾向にあります。価格は安定しており、中国や韓国での生産が...
1-(4-溴-3-氟苯基)-2-氯乙酮を含む廃棄物はどのように処理すべきですか?
1-(4-溴-3-氟苯基)-2-氯乙酮 (CAS番号: 1260857-14-4) の廃棄物は専門的な廃棄処理が必要です。まず、廃棄物は密閉された容器に収集し、...
苦参酚Kとは何ですか?
苦参酚Kは、CAS番号101236-49-1を持つ化合物で、主に天然由来の生薬から抽出されます。この化合物は、抗炎症作用や抗癌作用を持つことが報告されています。
POTASSIUM (1-(TERTBUTOXYCARBONYL)AZETIDIN-3-YL)TRIFLUOROBORATE を含む廃棄物はどのように処理すべきですか?
POTASSIUM (1-(TERTBUTOXYCARBONYL)AZETIDIN-3-YL)TRIFLUOROBORATE を含む廃棄物は、まず安全なエント...
4-庚基-4’-联苯羧酸の市場動向や研究トレンドはどうですか?
4-庚基-4’-聯苯羧酸は、特殊化学品や合成化学の分野で用いられる化学物質ですが、市場動向としては、研究開発の進展とともに需要が増加しています。また、環境配慮型...
6-ブロモ-3-メトキシ-1-フェニル-1H-インドゾールを含む廃棄物はどのように処理すべきですか?
6-ブロモ-3-メトキシ-1-フェニル-1H-インドゾールを含む廃棄物は、適切な化学廃棄処理が必要です。通常、廃棄物は密閉容器に収集され、専門の廃棄処理業者に引...
4,4-二甲基-2-吡咯烷酮はどの業界で使用されていますか?
4,4-二甲基-2-吡咯烷酮は医薬、ポリマー、センサー、半導体などの業界で広く使用されています。特に溶媒としての性能が高く評価されています。
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











![1-Naphthalenesulfonic acid, 2-[(2-hydroxy-1-naphthalenyl)azo]-, bariumsalt (2:1) structure 1-Naphthalenesulfonic acid, 2-[(2-hydroxy-1-naphthalenyl)azo]-, bariumsalt (2:1) structure](https://static.chemtradehub.com/structs/110/1103-38-4-0b33.webp)

![1,2-Diphenyl-4-[2-(phenylsulfinyl)ethyl]-3,5-pyrazolidinedione structure 1,2-Diphenyl-4-[2-(phenylsulfinyl)ethyl]-3,5-pyrazolidinedione structure](https://static.chemtradehub.com/structs/57-/57-96-5-efcc.webp)
