Living radical polymerization of vinyl acetate and methyl acrylate mediated by Co(Salen*) complexes

文献情報

出版日 2013-03-14

DOI 10.1039/C3PY00282A

インパクトファクター 5.582

著者

Chei-Ming Liao, Ching-Chun Hsu, Fu-Sheng Wang, Bradford B. Wayland, Chi-How Peng

原文を見る

要旨

Vinyl acetate and methyl acrylate living radical polymerization were successfully mediated by cobalt(II) Salen* complexes. Living characters of the polymerization are demonstrated by the linear increase in molecular weight with conversion, low polydispersity (1.14–1.27), and the formation of block copolymers. The equilibrium between cobalt(II) and organo-cobalt(III) species in methyl acrylate polymerization was followed by UV-vis spectroscopy and the equilibrium constant was determined to be 2.4 × 107 M−1.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Living radical polymerization of vinyl acetate and methyl acrylate mediated by Co(Salen*) complexes

文献情報

おすすめジャーナル

関連文献

Azolium hydrogen carbonates and azolium carboxylates as organic pre-catalysts for N-heterocyclic carbene-catalysed group transfer and ring-opening polymerisations

SET-LRP of hydrophobic and hydrophilic acrylates in trifluoroethanol

Polymerization behaviors and polymer branching structures in ATRP of monovinyl and divinyl monomers

Multifunctional poly(amine-ester)-type hyperbranched polymers: lipase-catalyzed green synthesis, characterization, biocompatibility, drug loading and anticancer activity

Front cover

Organoselenium compounds: development of a universal “living” free radical polymerization mediator

One-pot controlled synthesis of double thermoresponsive N-vinylcaprolactam-based copolymers with tunable LCSTs

Synthesis, photophysical and photovoltaic properties of a new class of two-dimensional conjugated polymers containing donor–acceptor chromophores as pendant groups

High-density and hetero-functional group engineering of segmented hyperbranched polymersvia click chemistry

UV- and NIR-responsive polymeric nanomedicines for on-demand drug delivery

こちらもおすすめ

2,5-二羧基氟苯の市場動向や研究トレンドはどうですか？

8-甲基-2-噻吩-2-基-喹啉-4-羧酸を含む廃棄物はどのように処理すべきですか？

2,4-二氯-6-甲基5-嘧啶甲醛の主な用途は何ですか？

レターメビールとは何ですか？

2-(1,3-二氧杂烷-2-基)噻唑の物理化学的性質は何ですか？

L-beta-高酪氨酸塩酸塩は安全ですか？

睡茄灯笼草素Cはどのように合成されますか？

4-(嘧啶-2-基)哌嗪-1-羧酸叔丁酯はどのように保存すればよいですか？

NBI-74330の主な用途は何ですか？

6-トリフルオロメチル-2-クロロピリジン-4-ボリリック酸はどのように合成されますか？

掲載誌

Polymer Chemistry

おすすめ化合物

Sodium Sulfite

Disodium oxidosulfanesulfonate oxide

Niacinamide

6-amino-1,3-dimethyl-1,2,3,4-tetrahydropyrimidine-2,4-dione

Acrylamide

おすすめサプライヤー