Triphenylphosphine as phosphorus catalyst for reversible chain-transfer catalyzed polymerization (RTCP)

文献情報

出版日 2013-03-04

DOI 10.1039/C3PY00187C

インパクトファクター 5.582

著者

Liangjiu Bai, Lifen Zhang, Yuan Liu, Xiangqiang Pan, Zhenping Cheng, Xiulin Zhu

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要旨

Triphenylphosphine (TPP) was used as the catalyst for reversible chain-transfer catalyzed polymerizations (RTCPs) of styrene and methyl methacrylate for the first time. The polymerizations showed the typical features of “living”/controlled radical polymerization, and well-defined polymers with designable molecular weights and narrow molecular weight distributions (Mw/Mn < 1.35) were obtained. In addition, RTCP of styrene using TPP as a novel catalyst not only could be conducted in the presence of a limited amount of air but also did not destroy the controllability over polymerizations.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

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Triphenylphosphine as phosphorus catalyst for reversible chain-transfer catalyzed polymerization (RTCP)

文献情報

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