Ring-opening polymerization of racemic β-butyrolactone promoted by rare earth trisborohydride complexes towards a PHB-diol: an experimental and DFT study

文献情報

出版日 2013-02-22

DOI 10.1039/C3PY00056G

インパクトファクター 5.582

著者

Sophie M. Guillaume, Liana Annunziata, Iker del Rosal, Christophe Iftner, Laurent Maron, Peter W. Roesky, Matthias Schmid

原文を見る

要旨

The ring-opening polymerization (ROP) of racemic β-butyrolactone (BL), catalyzed by the homoleptic lanthanide trisborohydride complexes, [Ln(BH4)3(THF)3] with Ln = La, Nd, and Sm, is reported, together with a DFT study of the polymerization mechanism. Well-defined atactic α,ω-dihydroxytelechelic poly(3-hydroxybutyrate)s (PHBs), PHB diols, are thus synthesized (Mn up to 8000 g mol−1, 1.02 ≤ Đ ≤ 1.10) as evidenced both experimentally and computationally. DFT investigations also emphasize the lack of stereoselectivity of the catalyst although a high activity is energetically evidenced.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Ring-opening polymerization of racemic β-butyrolactone promoted by rare earth trisborohydride complexes towards a PHB-diol: an experimental and DFT study

文献情報

おすすめジャーナル

関連文献

An “electrons-in-molecule’' model for atom–atom representation of atom–molecule potentials, with application to the Ar–B2(X3Σg-) complex

Accurate abinitio prediction of the rovibrational energy levels and equilibrium geometry of carbonyl selenide (OCSe)

Amine-containing diblock terpolymers via AROP: a versatile method for the generation of multifunctional micelles

Determination of the complex shear modulus of polymer solutions with piezoelectric resonators

Chromium silsesquioxane based synthesis and characterization of a microporous Cr–Si–O material

ATR-IR spectroscopic studies of the formation of sulfuric acid and sulfuric acid monohydrate films

The Ã2Σ+←2Π transition of the NO·CH4 and NO·CD4 complexes

Formation of bayerite, gibbsite and boehmite particles by laser ablation

Alkyne polymerization on the titanosilicate molecular sieve ETS-10

Molecular adsorption on the quasi-one-dimensional c(2 × 2)-Br/Pt(110) surface

こちらもおすすめ

除水剤ALT-201は安全ですか？

「邻羟基阿托伐他汀内酯标准品」に適用される法規ガイドelinesは何ですか？

メチル（3R）-3-アミノ-2,3-ジヒドロ-1-ベンゾファンラニン-5-カルボイル酸塩塩酸塩の主な用途は何ですか？

トランス-4-メチルピロリジン-3-オール塩酸塩はどのように合成されますか？

硫雜環丁烷-1,1-二氧化物は安全ですか？

ブラエリリンの主な用途は何ですか？

9-ヒドロキシエリプチシネ塩酸塩はどのように合成されますか？

5-塩素-2-(メチルアミノ)フェニル-(2-塩素フェニル)メタン酮の物理化学的性質は何ですか？

1-[2-(4-甲氧基-苯氧基)-乙基]-哌嗪はどのように保存すればよいですか？

2-[3-(4-甲氧基フェニル)プロピル]-4,4,5,5-四メチル-1,3,2-ドイボロロールアンの主な用途は何ですか？

掲載誌

Polymer Chemistry

おすすめ化合物

Niacinamide

Sodium Sulfite

1,1',1'',1'''-[Disulfanediylbis(carbonothioylnitrilo)]tetraethane

6-amino-1,3-dimethyl-1,2,3,4-tetrahydropyrimidine-2,4-dione

Isobutylboronic acid

おすすめサプライヤー