Iron based photoanodes for solar fuel production
文献情報
Prince Saurabh Bassi, Gurudayal, Lydia Helena Wong
In natural photosynthesis, the water splitting reaction of photosystem II is the source of the electrons/reducing equivalents for the reduction of carbon dioxide to carbohydrate while oxygen is formed as the by-product. Similarly, for artificial photosynthesis where the end product is a solar fuel such as hydrogen, a water splitting-oxygen evolving system is required to supply high energy electrons to drive the reductive reactions. Very attractive candidates for this purpose are iron based semiconductors which have band gaps corresponding to visible light and valence band energies sufficient to oxidise water. The most studied system is hematite (Fe2O3) which is highly abundant with many attributes for incorporation into photoelectrochemical (PEC) cells. We review the recent progress in manipulating hematite for this purpose through nanostructuring, doping and surface modifications. We also consider several hybrid iron-based semiconducting systems like ferrites and iron titanates as alternatives to hematite for light driven water splitting emphasizing their advantages with respect to their band levels and charge transport properties.
関連文献
Adsorption of PNIPAmx-PEO20-PPO70-PEO20-PNIPAmx pentablock terpolymer on gold surfaces: effects of concentration, temperature, block length, and surface properties
Tongquan Chen, Yanping Lu, Tianyou Chen, Xinghong Zhang, Binyang Du
DOI: 10.1039/C3CP54535K
Entropy and enthalpy contributions to the kinetics of proton coupled electron transfer to the Mn4O4(O2PPh2)6 cubane
Thomas G. Carrell, Paul F. Smith, Joseph Dennes, G. Charles Dismukes
DOI: 10.1039/C3CP55200D
Unimolecular reaction chemistry of a charge-tagged beta-hydroxyperoxyl radical
Sui So, Gabriel da Silva
DOI: 10.1039/C4CP02981J
Anomalous diffusion models and their properties: non-stationarity, non-ergodicity, and ageing at the centenary of single particle tracking
Andrey G. Cherstvy, Eli Barkai
DOI: 10.1039/C4CP03465A
Photocatalytic performance of TiO2–zeolite templated carbon composites in organic contaminant degradation
Metta Chareonpanich, Khanin Nueangnoraj, Hirotomo Nishihara, Takashi Kyotani
DOI: 10.1039/C4CP03897E
A novel photoelectrochemical flow cell with online mass spectrometric detection: oxidation of formic acid on a nanocrystalline TiO2 electrode
Robert Reichert, Zenonas Jusys, R. Jürgen Behm
DOI: 10.1039/C4CP03320E
Photosynthesis: from natural to artificial
Johannes Messinger, Wolfgang Lubitz, Jian-Ren Shen
DOI: 10.1039/C4CP90053G
Computational study on the interaction between CCR5 and HIV-1 entry inhibitor maraviroc: insight from accelerated molecular dynamics simulation and free energy calculation
Yang Zhang, Xiaomeng Li, Wenbo Chen, Huanxiang Liu, Xiaojun Yao
DOI: 10.1039/C4CP03331K
Aggregation of nitroaniline in tetrahydrofuran through intriguing H-bond formation by sodium borohydride
Mainak Ganguly, Chanchal Mondal, Anjali Pal, Saied Md Pratik, Jaya Pal, Tarasankar Pal
DOI: 10.1039/C4CP00497C
こちらもおすすめ
1-{3-[5-(エチルカルボンイル)-2,4-ジメチル-1H-ピロロール-3-基]プロパニル}ピペリジン-4-カルボン酸について、適用される法規ガイドラインは何ですか?
この化合物はCAS番号1142209-81-1であり、GHS分類では corrosive (腐食性物質) と classified (分類物質) として指定され...
2,2-二氟-1,3-ベンゾジオキサン-5-カルボキシlic酸とは何ですか?
2,2-二氟-1,3-ベンゾジオキサン-5-カルボキシlic酸は、CAS番号656-46-2の化合物で、化学式はC8H4F2O4です。この化合物は白色の結晶性粉...
8-氯-4-色原酮の代替品はありますか?
8-氯-4-色原酮(CAS番号: 49701-11-3)の代替品には、他の色原酮類似物や、構造が似ている化合物があります。例えば、8-メチル-4-色原酮や、他の...
エチル6,6-ジメチル-4,5,6,7-テトラヒドロ-1H-インドアゼー-3-カルボキシレートとは何ですか?
エチル6,6-ジメチル-4,5,6,7-テトラヒドロ-1H-インドアゼー-3-カルボキシレートは、CAS番号1233243-56-5を有する化合物です。これは有...
4-叔丁基-6-氯-嘧啶に適用される法規ガイドラインは何ですか?
4-叔丁基-6-氯-嘧啶はCAS番号3435-24-3で、GHS分類では毒性物質とみなし、GHSの危険性分類が適用されます。REACH規則では登録が必要で、Eu...
維库溴铵杂质Bはどのように合成されますか?
維库溴铵杂质Bは、アンドロステンデンから始まり、一連の合成反応、包括的な選択性と高い収率で合成されます。具体的には、ブロミド化、酸化、ジマーゼ反応、アミド化など...
2-(4-氟苄基)-吡咯烷の物理化学的性質は何ですか?
CAS番号350017-04-8の2-(4-氟苄基)-吡咯烷は、結晶性の白色粉末です。分子量は199.17 g/molで、水に溶けにくいです。化学反応では比較的...
3-喹啉甲醛(2-チロール-8-エチル)は安全ですか?
3-喹啉甲醛(2-チロール-8-エチル)は一定の毒性を持つため、取扱には注意が必要です。使用する際は適切な防護具を着用し、密閉容器で保管・搬送し、直接的な接触を...
エチル3-(ヒドロキシメチル)-1H-ピロール-2-カルボキシレートはどのように保存すればよいですか?
エチル3-(ヒドロキシメチル)-1H-ピロール-2-カルボキシレートは、室温(25℃)以下で保存し、直射日光を避け、乾燥した環境で保管することが推奨されます。ま...
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.












![2-Bromodibenzo[b,d]furan structure 2-Bromodibenzo[b,d]furan structure](https://static.chemtradehub.com/structs/86-/86-76-0-1814.webp)

