Far-infrared spectra of well-defined thiolate-protected gold clusters

文献情報

出版日 2013-10-07

DOI 10.1039/C3CP53845A

インパクトファクター 3.676

著者

Igor Dolamic, Birte Varnholt, Thomas Bürgi

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要旨

The far infrared spectra of a series of well-defined gold clusters covered with 2-phenylethanethiolate were studied. The spectra of the clusters are different but the differences are subtle. The Au–S stretching vibrations give rise to bands around 300 cm−1 and below. The relative intensity of these bands changes but they shift only slightly for different clusters. A low-frequency band was identified, which is sensitive to the conformation (trans/gauche) of the 2-phenylethanethiolate ligand.

掲載誌

Physical Chemistry Chemical Physics

CiteScore: 5.5

自己引用率: 10.3%

年間論文数: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.