Bistable memory devices with lower threshold voltage by extending the molecular alkyl-chain length
文献情報
Wusheng Ren, Yongxiang Zhu, Jianfeng Ge, Xufeng Xu, Ru Sun, Najun Li, Hua Li, Qingfeng Xu, Junwei Zheng, Jianmei Lu
Three organic small molecules with alkyl chains of different lengths based on an azobenzene scaffold were designed and synthesized. The indium-tin oxide (ITO)–Azo–Al sandwich memory devices showed write-once-read-many-times (WORM) characteristics. The switch threshold voltage of Azo-based memory devices significantly decreased as the end-capping alkyl chain extends, which is totally consistent with the AFM and X-ray diffraction results that the thin films showed smoother morphologies and closer intermolecular packing with the molecular alkyl-chain length prolonging. These results demonstrated that variation in the alkyl-chain length at the end of the conjugated molecules is a powerful strategy for tuning film microstructure and intermolecular packing to enable high performance of the fabricated sandwiched devices.
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