Coordination self-assembly of bromo-phenyl and pyridyl functionalized porphyrins with Fe on an Au(111) surface
文献情報
Xiao Feng Mao, Tao Lin, Jinne Adisoejoso, Ziliang Shi, Xue Song Shang, Pei Nian Liu, Nian Lin
Using scanning tunneling microscopy, the coordination self-assembly of a series of peripheral bromo-phenyl and pyridyl substituted porphyrins with Fe was studied on an Au(111) surface. The porphyrins functionalized with two trans-pyridyl groups afford extended hexagonal frameworks and the porphyrins functionalized with three pyridyl groups generate discrete rosette and extended chiral kagome framework structures. The self-assembly of the porphyrin derivatives in which phenyl groups are substituted by bromo-phenyl results in coordination networks exhibiting identical structures to that of the parent compounds. These structures contain nanocavities decorated with Br, which provide potential for covalent functionalization.
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