High-precision measurement-based correlation studies among atomic force microscopy, Rayleigh scattering, and surface-enhanced Raman scattering at the single-molecule level

文献情報

出版日 2013-01-08

DOI 10.1039/C3CP43817A

インパクトファクター 3.676

著者

Hae Mi Lee, Jung-Hoon Lee, Hyung Min Kim, Seung Min Jin, Hyo Sun Park, Jwa-Min Nam, Yung Doug Suh

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要旨

We investigated the correlations among the structure, Rayleigh scattering, and single-molecule surface-enhanced Raman scattering (SERS) of DNA-tethered Au–Ag core–shell nanoparticles, especially in dimer and trimer forms. For the optimal correlation measurements, accurate information on the position of the nanoparticle is crucial for locating the nanoparticle at the center of the excitation source for the optical measurements. To achieve this, we developed a multistep correlation strategy that enables us to unambiguously correlate the AFM images with optical images within a few nanometers. We also newly defined the correlation accuracy in this paper as a useful concept for the correlation measurements. With this reliable correlation accuracy, we performed various statistical analyses to thoroughly elucidate the relationships between particle structure, Rayleigh scattering and SERS in terms of the incident polarization and scattering intensity ratio.

掲載誌

Physical Chemistry Chemical Physics

CiteScore: 5.5

自己引用率: 10.3%

年間論文数: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.