Resonance enhanced multiphoton ionization spectroscopy of NHD2via the 1E′′-state
文献情報
Chung-Hsin Yang, Gautam Sarma, Ashim Kumar Saha, David H. Parker, Colin M. Western
Rotational analysis of the (2 + 1) resonance enhanced multiphoton ionization (REMPI) spectrum of the 1E′′ Rydberg state of the ammonia isotopologue NHD2 is reported. While the electronic degeneracy is lifted in NHD2 the splitting is small enough that interactions between the two states must be considered, particularly to model the intensity of the transitions. A simple model is developed to account for these interactions, relating them to terms present in the symmetric isotopologues. Spectroscopic parameters for the zero point and (ν2′ = 1–6) vibrational levels of the B 1E′′ state have been derived using this model and the spectra are accurately simulated for the first time using the PGOPHER program. The current work provides the basis for on-going velocity map imaging studies of rotational energy transfer in the mixed isotopologues of ammonia.
おすすめジャーナル

Nature

Journal of Organometallic Chemistry

Proceedings of the National Academy of Sciences of the United States of America

European Journal of Wood and Wood Products

Molecular Pharmacology

Science Progress

Journal of Physics and Chemistry of Solids

Russian Chemical Reviews

Kinetics and Catalysis

Fibre Chemistry
関連文献
Infrared laser-assisted desorption electrospray ionization mass spectrometry
Yohannes H. Rezenom, Jianan Dong, Kermit K. Murray
DOI: 10.1039/B715146B
Evaluation of partial least-squares with second-order advantage for the multi-way spectroscopic analysis of complex biological samples in the presence of analyte–background interactions
María J. Culzoni, Héctor C. Goicoechea, Ariana P. Pagani, Miguel A. Cabezón, Alejandro C. Olivieri
DOI: 10.1039/B603383K
Intrinsic charge ladders of a monoclonal antibody in hydroxypropylcellulose-coated capillaries
Rohan D. Sanzgiri, Tracy A. McKinnon, Brian T. Cooper
DOI: 10.1039/B603441A
Separation and detection of individual submicron particles by capillary electrophoresis with laser-light-scattering detection
Yohannes H. Rezenom, Amber D. Wellman, Luanne Tilstra, Colin D. Medley, S. Douglass Gilman
DOI: 10.1039/B709509K
SERS detection of environmental pollutants in humic acid–gold nanoparticle composite materials
Ramon A. Alvarez-Puebla, David S. dos Santos, Jr., Ricardo F. Aroca
DOI: 10.1039/B711361G
Investigation of binding event perturbations caused by elevated QCM-D oscillation amplitude
Malin Edvardsson, Michael Rodahl, Fredrik Höök
DOI: 10.1039/B601800A
Molecular composition of iron oxide nanoparticles, precursors for magnetic drug targeting, as characterized by confocal Raman microspectroscopy
Igor Chourpa, Laurence Douziech-Eyrolles, Lazare Ngaboni-Okassa, Jean-François Fouquenet, Simone Cohen-Jonathan, Martin Soucé, Hervé Marchais, Pierre Dubois
DOI: 10.1039/B419004A
Measurement of dielectrophoretic mobility of single micro-particles in a flow channel
Ikuhiro Ikeda, Hideaki Monjushiro, Hitoshi Watarai
DOI: 10.1039/B508498A
Angular-dependent metal-enhanced fluorescence from silver colloid-deposited films: opportunity for angular-ratiometric surface assays‡
Kadir Aslan, Stuart N. Malyn, Chris D. Geddes
DOI: 10.1039/B709170B
Scanning electrochemical microscopy coupled with intracellular standard addition method for quantification of enzyme activity in single intact cells
Ning Gao, Xiaolei Wang, Lu Li, Xiaoli Zhang, Wenrui Jin
DOI: 10.1039/B707532D
こちらもおすすめ
3-(5-フェニル-2-ファイル)-プロパン酸の市場動向や研究トレンドはどうですか?
この化合物の市場動向は不明ですが、類似化合物の需要は化学繊維、医薬品、農薬分野で安定しています。研究トレンドとしては、該当化合物の生物学的活性の評価や、その他の...
3- Chloro-1H-indazol-5-olはどのように保存すればよいですか?
3- チロロ-1H-吲唑-5-醇は遮光し、直射日光を避けて、温度は室温を推奨し、密閉容器に保存してください。
L-(1-~13~C)メチオニンの市場動向や研究トレンドはどうですか?
L-(1-~13~C)メチオニンは、医薬品やバイオテクノロジー分野での研究が増加しており、その価格は安定しています。新興研究分野では、代謝解析や遺伝子機能解析で...
1,3-フェニレンビスメチレンビスアクリレートは安全ですか?
1,3-フェニレンビスメチレンビスアクリレートは一般的に安全ですが、直接皮膚に触れる場合は保護用具を使用することを推奨します。高濃度の蒸気が吸入された場合は呼吸...
丹参醇Aはどのように保存すればよいですか?
丹参醇Aは、直射日光を避けて室温で保存し、密栓容器に入れることをお勧めします。適切な保存条件は、安定性を保ち、安全性を確保する上で重要です。
4-メチル-2-(1,1,1-三フロロ-2-メチルプロパニル)ピリドインとは何ですか?
CAS番号1378865-93-0の4-メチル-2-(1,1,1-三フロロ-2-メチルプロパニル)ピリドインは、合成化学分野で用いられる有機化合物の一種です。こ...
N-フェニルベンジル-2-クロロ酢氨を取り扱う際の実験室安全事項は何ですか?
N-フェニルベンジル-2-クロロ酢氨は毒性があり、皮膚や粘膜に刺激を与えます。取り扱う際には、保護眼鏡、手袋、ゴーグルを着用することを強く推奨します。ドラフトチ...
UCN-02を取り扱う際の実験室安全事項は何ですか?
UCN-02は毒性は低いですが、人体への直接的な接触は避けるべきです。PPE要件はグローブと顔面保護具を着用することです。ドラフトチャンバーを使用して漏洩を処理...
N-[3-[2-(二甲基氨基)乙氧基]-4-甲氧基苯基]-2'-甲基-4'-(5-甲基-1,2,4-恶二唑-3-基)-[1,1'-联苯]-4-甲酰胺を取り扱う際の実験室安全事項は何ですか?
手袋と保護眼鏡を着用し、漏洩時には吸気防止装置を使用してください。室温、乾燥した場所に保管し、直日光から隔離してください。SDS(安全データシート)を参照してく...
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.




![5-Bromoimidazo[1,2-a]pyridine structure 5-Bromoimidazo[1,2-a]pyridine structure](https://static.chemtradehub.com/structs/692/69214-09-1-d8e2.webp)