Controlled construction of hierarchical Co1−xS structures as high performance anode materials for lithium ion batteries
文献情報
Fei Liang, Limin Wang
Novel 3D hierarchical flower-like Co1−xS architectures were successfully synthesized via a hydrothermal process using trisodium citrate (Na3Cit) as a chelating agent. The crystal structure and morphology of the as-prepared products were characterized and the results demonstrated that the Na3Cit could efficiently control the formation of flower-like Co1−xS hierarchitectures. A possible growth mechanism for this hierarchical flower-like Co1−xS nanostructure was proposed on the basis of a series of time-dependent experiments, and this work provides an efficient route for designing desirable micro-/nanostructures. The flower-like Co1−xS nanostructures were fabricated as anode materials of lithium ion batteries and tested in the range of 0.01 V–3.00 V. The initial discharge capacity was up to 1244 mAh g−1 at the current density of 50 mA g−1. The electrochemical measurement suggested that the flower-like Co1−xS nanostructures have high capacity and excellent cycle stability as a Li-ion battery anode.
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CrystEngComm

CrystEngComm is the forum for the design and understanding of crystalline materials. We welcome studies on the investigation of molecular behaviour within crystals, control of nucleation and crystal growth, engineering of crystal structures, and construction of crystalline materials with tuneable properties and functions. We publish hypothesis-driven research into… how crystal design affects thermodynamics, phase transitional behaviours, polymorphism, morphology control, solid state reactivity (crystal-crystal solution-crystal, and gas-crystal reactions), optoelectronics, ferroelectric materials, non-linear optics, molecular and bulk magnetism, conductivity and quantum computing, catalysis, absorption and desorption, and mechanical properties. Using Techniques and methods including… Single crystal and powder X-ray, electron, and neutron diffraction, solid-state spectroscopy, spectrometry, and microscopy, modelling and data mining, and empirical, semi-empirical and ab-initio theoretical evaluations. On crystalline and solid-state materials. We particularly welcome work on MOFs, coordination polymers, nanocrystals, host-guest and multi-component molecular materials. We also accept work on peptides and liquid crystals. All papers should involve the use or development of a design or optimisation strategy. Routine structural reports or crystal morphology descriptions, even when combined with an analysis of properties or potential applications, are generally considered to be outside the scope of the journal and are unlikely to be accepted.










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