Syntheses, structures and luminescence properties of three metal–organic frameworks based on 5-(4-(2H-tetrazol-5-yl)phenoxy)isophthalic acid
文献情報
Hongming He, Fuxing Sun, Hongmin Su, Jiangtao Jia, Qin Li
Three metal–organic frameworks (MOFs), namely [Zn2(TPIA)(OH)(H2O)]·H2O (JUC-114), [Cd2(TPIA)(OH)(H2O)2]·H2O (JUC-115), and [Co2(TPIA)(OH)(H2O)2]·H2O (JUC-116) (JUC = Jilin University China), based on a new ligand, 5-(4-(2H-tetrazol-5-yl)phenoxy)isophthalic acid (H3TPIA), were synthesized under hydrothermal conditions and characterized by single crystal X-ray diffraction, elemental analysis, IR spectroscopy, TGA analysis and powder X-ray diffraction. JUC-114, JUC-115 and JUC-116 all possess 3D frameworks with (4,8)-connected fluorite (flu) topology based on similar tetranuclear metal centers as secondary building unit (SBU). Furthermore, the luminescence of the ligand H3TPIA and compounds was measured at room temperature.
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CrystEngComm

CrystEngComm is the forum for the design and understanding of crystalline materials. We welcome studies on the investigation of molecular behaviour within crystals, control of nucleation and crystal growth, engineering of crystal structures, and construction of crystalline materials with tuneable properties and functions. We publish hypothesis-driven research into… how crystal design affects thermodynamics, phase transitional behaviours, polymorphism, morphology control, solid state reactivity (crystal-crystal solution-crystal, and gas-crystal reactions), optoelectronics, ferroelectric materials, non-linear optics, molecular and bulk magnetism, conductivity and quantum computing, catalysis, absorption and desorption, and mechanical properties. Using Techniques and methods including… Single crystal and powder X-ray, electron, and neutron diffraction, solid-state spectroscopy, spectrometry, and microscopy, modelling and data mining, and empirical, semi-empirical and ab-initio theoretical evaluations. On crystalline and solid-state materials. We particularly welcome work on MOFs, coordination polymers, nanocrystals, host-guest and multi-component molecular materials. We also accept work on peptides and liquid crystals. All papers should involve the use or development of a design or optimisation strategy. Routine structural reports or crystal morphology descriptions, even when combined with an analysis of properties or potential applications, are generally considered to be outside the scope of the journal and are unlikely to be accepted.














