Syntheses of three members of A(II)M(IV)(PO4)2: luminescence properties of PbGe(PO4)2 and its Eu3+-doped powders
文献情報
Wei-Long Zhang, Chen-Sheng Lin, Zhang-Zhen He, Hao Zhang, Zhong-Zhen Luo, Wen-Dan Cheng
We present here the syntheses and optical properties of three phosphates, namely, AM(PO4)2 (A = Pb2+, M = Ti, Ge; A = Sr2+, M = Ge). Thereinto, PbGe(PO4)2 features a strong green broad-band emission peaking at 508 nm at room temperature when excited by UV irradiation. Its luminescence properties, decay time and Commission Internationale de l'Éclairage (CIE) chromaticity index have been determined. Additionally, the photoluminescent properties of its Eu3+-doped powders have also been investigated. Finally, the calculations of energy band structure and density of states have been performed to construct an available model to explain a possible mechanism of electron transition.
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CrystEngComm is the forum for the design and understanding of crystalline materials. We welcome studies on the investigation of molecular behaviour within crystals, control of nucleation and crystal growth, engineering of crystal structures, and construction of crystalline materials with tuneable properties and functions. We publish hypothesis-driven research into… how crystal design affects thermodynamics, phase transitional behaviours, polymorphism, morphology control, solid state reactivity (crystal-crystal solution-crystal, and gas-crystal reactions), optoelectronics, ferroelectric materials, non-linear optics, molecular and bulk magnetism, conductivity and quantum computing, catalysis, absorption and desorption, and mechanical properties. Using Techniques and methods including… Single crystal and powder X-ray, electron, and neutron diffraction, solid-state spectroscopy, spectrometry, and microscopy, modelling and data mining, and empirical, semi-empirical and ab-initio theoretical evaluations. On crystalline and solid-state materials. We particularly welcome work on MOFs, coordination polymers, nanocrystals, host-guest and multi-component molecular materials. We also accept work on peptides and liquid crystals. All papers should involve the use or development of a design or optimisation strategy. Routine structural reports or crystal morphology descriptions, even when combined with an analysis of properties or potential applications, are generally considered to be outside the scope of the journal and are unlikely to be accepted.














